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7397-46-8 - Diethylmethoxyborane, 1M soln in THF - L15107 - Alfa Aesar

L15107 Diethylmethoxyborane, 1M soln in THF

CAS Number
7397-46-8
Synonyms

Size Price ($) Quantity Availability
25ml 33.06
100ml 76.53
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Diethylmethoxyborane, 1M soln in THF

MDL
MFCD00013240

Chemical Properties

Formula
C5H13BO
Formula Weight
99.97
Flash Point
-6°(21°F)
Density
0.868
Refractive Index
1.4040
Sensitivity
Air & Moisture Sensitive

Literature References

Has been used in combination with sodium borohydride for selective reductions: ß-hydroxy ketones are reduced with high diastereoselectivity to syn-diols: Tetrahedron Lett., 28, 155 (1987); ß δ-diketo esters are reduced to ß δ-dihydroxy esters without reduction of a conjugated olefinic double bond: Tetrahedron Lett., 29, 6467 (1988).

/n

GHS Hazard and Precautionary Statements

Hazard Statements: H225-H314-H351-H373-H317-H335-H303-H333

Highly flammable liquid and vapour. Causes severe skin burns and eye damage. Suspected of causing cancer. May cause damage to organs through prolonged or repeated exposure. May cause an allergic skin reaction. May cause respiratory irritation. May be harmful if swallowed. May be harmful if inhaled.

Precautionary Statements: P210-P260-P201-P261-P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dust/fume/gas/mist/vapours/spray. Obtain special instructions before use. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
2231225
Hazard Class
3
Packing Group
II
Harmonized Tariff Code
2931.90
TSCA
Yes
RTECS
ED6151000

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