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L15107 Diethylmethoxyborane, 1M soln in THF

CAS Number
7397-46-8
Synonyms

Stock No. Size Price ($) Quantity Availability
L15107-AC 25ml 31.30
L15107-AE 100ml 71.80
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Diethylmethoxyborane, 1M soln in THF

MDL
MFCD00013240

Chemical Properties

Formula
C5H13BO
Formula Weight
99.97
Flash Point
-6°(21°F)
Density
0.868
Refractive Index
1.4040
Storage & Sensitivity
Moisture Sensitive. Air Sensitive. Store under Argon. Ambient temperatures.

Literature References

Has been used in combination with sodium borohydride for selective reductions: ß-hydroxy ketones are reduced with high diastereoselectivity to syn-diols: Tetrahedron Lett., 28, 155 (1987); ß δ-diketo esters are reduced to ß δ-dihydroxy esters without reduction of a conjugated olefinic double bond: Tetrahedron Lett., 29, 6467 (1988).

/n

GHS Hazard and Precautionary Statements

Hazard Statements: H225-H250-H302-H314-H317-H335-H336-H351-H373

Highly flammable liquid and vapour. Catches fire spontaneously if exposed to air. Harmful if swallowed. Causes severe skin burns and eye damage. May cause an allergic skin reaction. May cause respiratory irritation. May cause drowsiness or dizziness. Suspected of causing cancer. May cause damage to organs through prolonged or repeated exposure.

Precautionary Statements: P201-P202-P210-P222-P233-P235-P240-P241-P242-P243-P260-P264b-P270-P271-P272-P280g-P281-P302+P334-P304+P340-P305+P351+P338-P310-P330-P331-P333+P313-P363-P370+P378q-P501c

Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not allow contact with air. Keep container tightly closed. Keep cool. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Contaminated work clothing should not be allowed out of the workplace. Wear protective gloves. Use personal protective equipment as required. IF ON SKIN: Immerse in cool water/wrap in wet bandages. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Rinse mouth. Do NOT induce vomiting. If skin irritation or rash occurs: Get medical advice/attention. Wash contaminated clothing before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
2231225
Hazard Class
3
Packing Group
II
Harmonized Tariff Code
2931.90
TSCA
Yes
RTECS
ED6151000

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