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Triethylborane is catalyst for allylation of aldehydes, decarboxylative C-C bond cleavage reactions, rhenium hydride / boron Lewis acid cocatalysis of alkene hydrogenations, Regioselective hydroxyalkylation of unsaturated oxime ethers. Reactant for radical reductions of alkyl bromides with N-heterocyclic carbene boranes and synthesis of tetramethylammonium trialkylphenylborate salts with oxidation potential.
Yanfeng Jiang; Jeannine Hess; Thomas Fox; Heinz Berke. Rhenium hydride/boron Lewis acid cocatalysis of alkene hydrogenations: activities comparable to those of precious metal systems. Journal of the American Chemical Society.2010, 132,(51), 18233-18247.
Masafumi Ueda et. al. Aerobic hydroxylation of N-borylenamine: triethylborane-mediated hydroxyalkylation of alpha,beta-unsaturated oxime ether. Organic Letters,2009,
Radical initiator for hydrostannylation of alkynes: Tetrahedron, 45, 923 (1989).
Reacts with metal enolates to give the enoxytriethylborates, useful in selective alkylation and aldol reactions: Tetrahedron Lett., 2975 (1976); 32, 5521 (1991).
Hazard Statements: H225-H314-H318
Highly flammable liquid and vapour. Causes severe skin burns and eye damage. Causes serious eye damage.
Precautionary Statements: P210-P280-P305+P351+P338-P309-P310a
Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF exposed or if you feel unwell: Immediately call a POISON CENTER/doctor