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14593-46-5 - Sodium tert-pentyloxide, 95% - Sodium tert-amylate - Sodium 2-methyl-2-butoxide - L15112 - Alfa Aesar

L15112 Sodium tert-pentyloxide, 95%

CAS Number
14593-46-5
Synonyms
Sodium tert-amylate
Sodium 2-methyl-2-butoxide

Size Price ($) Quantity Availability
25g 27.00
100g 52.70
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Sodium tert-pentyloxide, 95%

MDL
MFCD00064245
EINECS
238-369-4

Chemical Properties

Formula
C5H11NaO
Formula Weight
110.13
Sensitivity
Air & Moisture Sensitive
Solubility
Reacts with water.

Applications

Sodium tert-pentyloxide is a effective base for the alkylation of ketones.

Notes

Air and Moisture Sensitive, store away form air and water/moisture. Store in cool. Keep container tightly closed in a dry and well-ventilated place. Store away from oxidizing agent.

Literature References

I. N. Nazarov; S. N. Ananchenko; I. V. Torgov. Condensation of 1-vinylcyclohexene with propiolic and tetrolic acids and esters. Bulletin of the Academy of Sciences of the USSR, Division of chemical science.1959, 8,(1), 84-90.

Strong, hydrocarbon-soluble base: J. Organomet. Chem., 364, 281 (1989). Useful base for the Wittig reaction: Tetrahedron Lett., 31, 635 (1990).

In combination with LDA forms a 'superbasic ' reagent: Synthesis, 1493 (1995).

GHS Hazard and Precautionary Statements

Hazard Statements: H228-H251-H314-H318

Flammable solid. Self-heating: may catch fire. Causes severe skin burns and eye damage. Causes serious eye damage.

Precautionary Statements: P210-P260u-P303+P361+P353-P305+P351+P338-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dusts or mists. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
3983987
Hazard Class
4.2
Packing Group
II
Harmonized Tariff Code
2905.19
TSCA
Yes

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