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L15112 Sodium tert-pentyloxide, 95%

CAS Number
14593-46-5
Synonyms
Sodium tert-amylate
Sodium 2-methyl-2-butoxide

Stock No. Size Price ($) Quantity Availability
L15112-14 25g 28.00
L15112-22 100g 54.80
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Sodium tert-pentyloxide, 95%

MDL
MFCD00064245
EINECS
238-369-4

Chemical Properties

Formula
C5H11NaO
Formula Weight
110.13
Storage & Sensitivity
Moisture Sensitive. Air Sensitive. Ambient temperatures.
Solubility
Reacts with water.

Applications

Sodium tert-pentyloxide is a effective base for the alkylation of ketones.

Notes

Air and Moisture Sensitive, store away form air and water/moisture. Store in cool. Keep container tightly closed in a dry and well-ventilated place. Store away from oxidizing agent.

Literature References

I. N. Nazarov; S. N. Ananchenko; I. V. Torgov. Condensation of 1-vinylcyclohexene with propiolic and tetrolic acids and esters. Bulletin of the Academy of Sciences of the USSR, Division of chemical science.1959, 8,(1), 84-90.

Strong, hydrocarbon-soluble base: J. Organomet. Chem., 364, 281 (1989). Useful base for the Wittig reaction: Tetrahedron Lett., 31, 635 (1990).

In combination with LDA forms a 'superbasic ' reagent: Synthesis, 1493 (1995).

GHS Hazard and Precautionary Statements

Hazard Statements: H228-H312+H332-H314-H335-X

Flammable solid. Harmful in contact with skin. Harmful if inhaled. Causes severe skin burns and eye damage. May cause respiratory irritation.

Precautionary Statements: P210-P235+P410-P240-P241-P260-P264b-P271-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep cool. Protect from sunlight. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Wash contaminated clothing before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
3983987
Hazard Class
4.2
Packing Group
II
Harmonized Tariff Code
2905.19
TSCA
Yes

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