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2-Iodobenzyl alcohol was used in the synthesis of substituted seven-membered lactones, 2-[(E)-(1?-iodo-2?-propenyl)]benzyl alcohol2 and 2,3-diphenyl-1-indenone.
Dinesh Kumar Rayabarapu; and Chien-Hong Cheng. Synthesis of seven-membered lactones via nickel- and zinc-catalyzed highly regio- and stereoselective cyclization of 2-iodobenzyl alcohols with propiolates. Journal of the American Chemical Society.2002, 124,(20), 5630-5631.
Wang, G.; et al. Zirconium-catalyzed methylalumination of heterosubstituted arylethynes. Factors affecting the regio-, stereo-, and chemoselectivities. J. Organomet. Chem.2007, 692,4731.
Hazard Statements: H315-H319
Causes skin irritation. Causes serious eye irritation.
Precautionary Statements: P280a-P264-P305+P351+P338-P321-P332+P313-P337+P313
Wear protective gloves and eye/face protection. Wash thoroughly after handling. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Specific treatment (see label). If skin irritation occurs: Get medical advice/attention. If eye irritation persists: