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37342-97-5 - Bis(cyclopentadienyl)zirconium hydridochloride, 95% - Schwartz's Reagent - Zirconocene chloride hydride - L15164 - Alfa Aesar

L15164 Bis(cyclopentadienyl)zirconium hydridochloride, 95%

CAS Number
37342-97-5
Synonyms
Schwartz's Reagent
Zirconocene chloride hydride

Size Price ($) Quantity Availability
1g 31.60
5g 96.10
25g 345.00
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Bis(cyclopentadienyl)zirconium hydridochloride, 95%

MDL
MFCD02089401
EINECS
253-479-5

Chemical Properties

Formula
C10H11ClZr
Formula Weight
257.87
Melting point
>300°
Sensitivity
Light, Air & Moisture Sensitive
Solubility
Reacts with water.

Applications

Bis(cyclopentadienyl)zirconium hydridochloride is used in the conversion of amides to aldehydes. It is also used as a pharmaceutical intermediate.

Notes

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Handle and store under inert gas. It is sensitive to moisture, light and air. Incompatible with oxidizing agents.

Literature References

Jared T Spletstoser.; Jonathan M White.; Ashok Rao Tunoori.; Gunda I Georg. Mild and selective hydrozirconation of amides to aldehydes using Cp2Zr(H)Cl: scope and mechanistic insight.. Journal of the American Chemical Society. 2007, 129 (11), 3408-3419.

Thomas E. Cole.; Ramona. Quintanilla.; Stephan. Rodewald. Migration of 1-alkenyl groups from zirconium to boron compounds. Organometallics. 1991, 10 (10), 3777-3781.

GHS Hazard and Precautionary Statements

Hazard Statements: H228-H261-H314-H318

Flammable solid. In contact with water releases flammable gas. Causes severe skin burns and eye damage. Causes serious eye damage.

Precautionary Statements: P210-P231+P232-P260-P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Handle under inert gas. Protect from moisture. Do not breathe dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Merck
14,8396
Hazard Class
4.3
Packing Group
II
Harmonized Tariff Code
2931.90
TSCA
No

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