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L15193 3-(Hydroxymethyl)benzeneboronic acid, 98%

CAS Number
87199-15-3
Synonyms
3-(Hydroxymethyl)phenylboronic acid

Stock No. Size Price ($) Quantity Availability
L15193-03 1g 45.60
L15193-06 5g 121.00
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3-(Hydroxymethyl)benzeneboronic acid, 98%

MDL
MFCD01317846

Chemical Properties

Formula
C7H9BO3
Formula Weight
151.96
Melting point
93-98°
Storage & Sensitivity
Ambient temperatures.
Solubility
Soluble in water.

Applications

Reactant used for copper-mediated trifluoromethylation, copper-catalyzed transformations from arylboronic acids in water, Mitsunobu, Suzuki, and amidation reactions with hydroxyphenylamino bromopyrazinecarboxylate. Reactant involved in the synthesis of biologically active molecules including Mycobacterium tuberculosis H37Rv chorismate mutase inhibitors via Suzuki coupling reactions, HIV protease inhibitors with antiviral activity against drug-resistant viruses, Pyrrole derivatives for use as PDE4B inhibitors.

Notes

Store in cool. Keep container tightly closed in a dry and well-ventilated place. Store away from oxidizing agent.

Literature References

Cheng-Pan Zhang et. al. Copper-mediated trifluoromethylation of arylboronic acids by trifluoromethyl sulfonium salts.. ChemicalCommunications.2011, 47,(33), 9516-9518.

Haijun Yang et. al. General copper-catalyzed transformations of functional groups from arylboronic acids in water. Chemistry: A European Journal.2011, 17, (20), 5652-5660.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P362-P501c

Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
8832019
Harmonized Tariff Code
2931.90
TSCA
No

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