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145240-28-4 - 4-n-Butylbenzeneboronic acid, 98% - 4-n-Butylphenylboronic acid - L15584 - Alfa Aesar

L15584 4-n-Butylbenzeneboronic acid, 98%

CAS Number
145240-28-4
Synonyms
4-n-Butylphenylboronic acid

Size Price ($) Quantity Availability
1g 44.70
5g 152.00
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4-n-Butylbenzeneboronic acid, 98%

MDL
MFCD02093926
EINECS
000-000-0

Chemical Properties

Formula
C10H15BO2
Formula Weight
178.04
Melting point
103-106°
Solubility
Soluble in methanol.

Applications

Reactant for Suzuki-Miyaura cross-couplings, NHC-Iron-catalyzed aerobic oxidative aromatic esterification of aldehydes, Palladium-catalyzed oxidative Heck-type reactions.

Notes

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents.

Literature References

Fernandes, R. R.; et al.Oxadiazoline and Ketoimine Palladium(II) Complexes as Highly Efficient Catalysts for Suzuki-Miyaura Cross-Coupling Reactions in Supercritical Carbon Dioxide. Adv. Synth. Catal. 2012, 353 1153-1160.

Hu Chen et. al. Nickel-catalyzed cross-coupling of aryl phosphates with arylboronic acids.. Journal of Organic Chemistry. 2011 76 (7), 2338-2344.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P280-P305+P351+P338-P304+P340-P362-P312-P321-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Specific treatment (see label). Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
6920034
Harmonized Tariff Code
2931.90
TSCA
No

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