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13061-96-6 - Methylboronic acid, 97% - Methaneboronic acid - L15589 - Alfa Aesar

L15589 Methylboronic acid, 97%

CAS Number
13061-96-6
Synonyms
Methaneboronic acid

Size Price ($) Quantity Availability
1g 43.80
5g 137.00
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Methylboronic acid, 97%

MDL
MFCD00002105

Chemical Properties

Formula
CH5BO2
Formula Weight
59.86
Melting point
89-94°
Sensitivity
Hygroscopic
Solubility
Soluble in water.

Applications

Reagent used for palladium-catalyzed stille and suzuki-miyaura cross-couplings, microwave-heated heterogeneous palladium (pd)-catalytized reactions, ruthenium (ru)-catalyzed silylation reactions, bis(aminotropone) titanium (ti) catalysts for ethylene polymerizations, enantioselective asymmetric bromoaminocyclization and bromoaminocyclization using amino-thiocarbamate catalysts. Reagent used in preparation of common building blocks for pharmaceuticals and agrochemicals, chrysin analogs by suzuki-miyaura coupling reactions, casein kinase i inhibitors, divergent c-h functionalizations directed by sulfonamide pharmacophores in drug discovery.

Notes

Hygroscopic.Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents, water, moisture.

Literature References

Ben W Glasspoole et. al. Suzuki-Miyaura cross-couplings of secondary allylic boronic esters.. Chemical Communications. 2012, 48 (9), 1230-1232 .

Hui-Xiong Dai et. al. Divergent C-H functionalizations directed by sulfonamide pharmacophores: late-stage diversification as a tool for drug discovery.. Journal of the American Chemical Society. 2011, 133 (18), 7222-7228.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P280g-P305+P351+P338

Wear protective gloves. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Other References

Beilstein
1731087
Harmonized Tariff Code
2931.90
TSCA
No

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