Cookies disclaimer

I agree Our site saves small pieces of text information (cookies) on your device in order to deliver better content and for statistical purposes. You can disable the usage of cookies by changing the settings of your browser. By browsing our website without changing the browser settings you grant us permission to store that information on your device.

71597-85-8 - 4-Hydroxybenzeneboronic acid, 97% - 4-Boronophenol - 4-Hydroxyphenylboronic acid - L15594 - Alfa Aesar

L15594 4-Hydroxybenzeneboronic acid, 97%

CAS Number
71597-85-8
Synonyms
4-Boronophenol
4-Hydroxyphenylboronic acid

Size Price ($) Quantity Availability
1g 41.32
5g 135.96
Add to Cart Add to Quote Request View Item

4-Hydroxybenzeneboronic acid, 97%

MDL
MFCD01074628
EINECS
000-000-0

Chemical Properties

Formula
C6H7BO3
Formula Weight
137.93
Melting point
ca 285° dec.
Solubility
Soluble in water

Applications

4-Hydroxybenzeneboronic acid is used for Suzuki-Miyaura coupling and Stille coupling and potential for introducing different alkyl groups, palladium-catalyzed aminocarbonylation and cross-coupling reactions, bio-supported palladium nanoparticles as phosphine-free catalyst for Suzuki reaction in water and Cu2O-catalyzed aerobic oxidative cross-coupling of tetrazoles. It is also used in preparation of rod-like dendronized polymers.

Notes

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Incompatible with oxidizing agents.

Literature References

Mayura Talwelkar.; V.R. Pedireddi. -B(OH)2 versus -OH in supramolecular synthesis: molecular complexes of 4-hydroxyphenylboronic acid with aza-donor compounds. Tetrahedron Letters. 2010, 51 (52), 6901-6905.

Shunpei Ishikawa.; Kei Manabe. Repetitive Two-step Method for Oligoarene Synthesis through Rapid Cross-coupling of Hydroxyphenylboronic Acids and Anhydrides. Chemistry Letters. 2006, 35 (2), 164-165.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P280-P305+P351+P338-P304+P340-P362-P312-P321-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Specific treatment (see label). Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
2963491
Harmonized Tariff Code
2931.90
TSCA
No

Recommended

  • A10249

    Tetra-n-butylammonium bromide, 98+%
  • A14237

    4-Bromobenzaldehyde, 98+%
  • A14333

    1-Bromoundecane, 98%
  • 19392

    Acetone, Semiconductor Grade, 99.5%
  • 30760

    Tetrahydrofuran, ACS, 99+%, stab. with 250ppm BHT

Recently Viewed

Chemicals

Life Science

Metals & Materials

Catalysts

Analytical & Labware