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N-Methyldiethanolamine is a reagent used for protection of boronic acids as N-methyl-O,O-diethanolamine esters.
Edward B. Rinker.; S.Ashour Sami.; Orville C. Sandall. Edward B. Rinker, S.Ashour Sami, Orville C. Sandall. Kinetics and modelling of carbon dioxide absorption into aqueous solutions of N-methyldiethanolamineChemical Engineering Science. 1995, 50 (5), 755-768.
Daniel P. Hagewiesche, Sami S. Ashour, Hani A. Al-Ghawas, Orville C. Sandall. Absorption of carbon dioxide into aqueous blends of monoethanolamine and N-methyldiethanolamine. Chemical Engineering Science. 1995, 50 (7), 1071-10795.
Reagent for protection of boronic acids as N-methyl-O,O-diethanolamine esters (cf Diethanolamine, A13389). The resulting derivatives have been converted to fluoroaromatics using cesium fluoroxysulfate: Synlett, 761 (1990); Tetrahedron, 48, 8073 (1992).
The boronic esters are also stable in the presence of organometallic (e.g. lithium derivatives): J. Org. Chem., 54, 4734 (1989).
Hazard Statements: H319
Causes serious eye irritation.
Precautionary Statements: P260-P201-P280i-P304+P340-P405-P501a
Do not breathe dust/fume/gas/mist/vapours/spray. Obtain special instructions before use. Wear eye/face protection. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.