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51429-74-4 - 12-Molybdophosphoric acid hydrate, Mo >47.5% - Molybdophosphoric acid - L15827 - Alfa Aesar

L15827 12-Molybdophosphoric acid hydrate, Mo >47.5%

CAS Number
51429-74-4
Synonyms
Molybdophosphoric acid

Size Price ($) Quantity Availability
25g 30.69
100g 78.07
500g 314.15
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12-Molybdophosphoric acid hydrate, Mo >47.5%

MDL
MFCD00149913
EINECS
234-713-5

Chemical Properties

Formula
H3PO4•12MoO3•xH2O
Formula Weight
1825.25(anhy)
Melting point
78-90°
Density
3.15
Sensitivity
Hygroscopic
Solubility
Soluble in water, ethanol and ether.

Applications

12-Molybdophosphoric acid hydrate is used as a precursor to hybrid organic-inorganic based molecular batteries with application as cation-insertion electrode. It finds application as an analytical reagent in thin layer chromatography for staining phenolics, hydrocarbon waxes, alkaloids and steroids. It acts as a reactant for the preparation of catalysts for the nitration of aromatic compounds, highly dispersed MoOx/CNTs (carbon nanotubes) as a support for Pt catalysts and anchored Wilkinson catalyst.

Notes

Hygroscopic. Incompatible with organic materials and powdered metals.

Literature References

Sharma, P.; Patel, A. Zirconia supported 12-molybdophosphoric acid: Physico-chemical characterization and non-solvent liquid phase oxidation of styrene. Appl. Surf. Sci. 2009, 55 (17), 7635-7641.

Fan, D.; Li, G.; Hao, J. Fabrication and electrocatalytic activities of porphyrin and 12-molybdophosphoric acid hybrid films. 2010, 351 (1), 151-155.

GHS Hazard and Precautionary Statements

Hazard Statements: H272-H314-H318

May intensify fire; oxidizer. Causes severe skin burns and eye damage. Causes serious eye damage.

Precautionary Statements: P221-P280-P305+P351+P338-P308+P313-P501a

Take any precaution to avoid mixing with combustibles. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF exposed or concerned: Get medical advice/attention. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Merck
14,7342
Hazard Class
5.1
Packing Group
III
Harmonized Tariff Code
2841.70
TSCA
Yes

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