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95407-69-5 - 4-Methoxy-TEMPO, free radical, 98+% - 4-Methoxy-2,2,6,6-tetramethylpiperidinyloxy, free radical - L15915 - Alfa Aesar

L15915 4-Methoxy-TEMPO, free radical, 98+%

CAS Number
95407-69-5
Synonyms
4-Methoxy-2,2,6,6-tetramethylpiperidinyloxy, free radical

Size Price ($) Quantity Availability
1g 46.10
5g 176.00
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4-Methoxy-TEMPO, free radical, 98+%

MDL
MFCD00270334
EINECS
000-000-0

Chemical Properties

Formula
C10H20NO2
Formula Weight
186.28
Melting point
39-41°

Literature References

Reviews: Synthesis and reactions of stable nitroxyl radicals: Synthesis, 190, 401 (1971); Advances in the chemistry of nitroxide spin labels: Chem. Rev., 78, 37 (1978); Recent advances in the chemistry of nitroxides and their applications in spin labelling: J. Sci. Ind. Res., 54, 623 (1995).

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The oxidation of alcohols to aldehydes has been effected catalytically, in the presence of a stoichiometric cooxidant such as ferricyanide: J. Mol. Catal., 31, 217 (1985), or with hypochlorite in a two-phase system: J. Org. Chem., 52, 2559 (1987). For a review of the use of stable nitroxyl radicals for the oxidation of primary and secondary alcohols, see: Synthesis, 1153 (1996).

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Compare also TEMPO, A12733 and 4-Acetamido-TEMPO, B23456.

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GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P280-P305+P351+P338-P304+P340-P362-P312-P321-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Specific treatment (see label). Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
4740399
Harmonized Tariff Code
2933.39
TSCA
No

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