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L15915 4-Methoxy-TEMPO, free radical, 98+%

CAS Number
95407-69-5
Synonyms
4-Methoxy-2,2,6,6-tetramethylpiperidinyloxy, free radical

Stock No. Size Price ($) Quantity Availability
L15915-03 1g 46.60
L15915-06 5g 169.00
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4-Methoxy-TEMPO, free radical, 98+%

MDL
MFCD00270334
EINECS
000-000-0

Chemical Properties

Formula
C10H20NO2
Formula Weight
186.28
Melting point
39-41°
Storage & Sensitivity
Ambient temperatures.

Literature References

Reviews: Synthesis and reactions of stable nitroxyl radicals: Synthesis, 190, 401 (1971); Advances in the chemistry of nitroxide spin labels: Chem. Rev., 78, 37 (1978); Recent advances in the chemistry of nitroxides and their applications in spin labelling: J. Sci. Ind. Res., 54, 623 (1995).

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The oxidation of alcohols to aldehydes has been effected catalytically, in the presence of a stoichiometric cooxidant such as ferricyanide: J. Mol. Catal., 31, 217 (1985), or with hypochlorite in a two-phase system: J. Org. Chem., 52, 2559 (1987). For a review of the use of stable nitroxyl radicals for the oxidation of primary and secondary alcohols, see: Synthesis, 1153 (1996).

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Compare also TEMPO, A12733 and 4-Acetamido-TEMPO, B23456.

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GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P337+P313-P362-P501c

Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
4740399
Harmonized Tariff Code
2933.39
TSCA
No

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