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Zinc trifluoromethanesulfonate acts as a catalyst for the preparation of dithioketals. It is used as a Lewis acid catalyst in silylation reactions. It is also used as a catalyst for greener amine synthesis by reductive amination with hydrogen gas.
Mild Lewis acid catalyst which promotes thioketalization, particularly of acid-sensitive substrates, with ethanedithiol: Tetrahedron Lett., 24, 169 (1983); J. Am. Chem. Soc., 105, 1662 (1983).
Useful, alone or in combination with TMS chloride, for glycosidation reactions: Chem. Pharm. Bull., 40, 2909 (1992); 41, 201 (1993); 42, 1808 (1994).
Promotes the aldol reaction of silyl enol ethers with aldehydes: Gazz. Chim. Ital., 123, 673 (1993).
In combination with N-methylephedrine, catalyzes enantioselective addition of terminal alkynes to aldehydes to give propargylic alcohols in high yield and ee: J. Am. Chem. Soc., 122, 1806 (2000).
Castro-Osma, J. A.; Comerford, J. W.; Heyn, R. H.; North, M.; Tangstad, E. New catalysts for carboxylation of propylene glycol to propylene carbonate via high-throughput screening. Faraday Discuss. 2015, 183, 19-30.
Sownthari, K.; Suthanthiraraj, S. A. Influence of Al2O3 nanofiller on the properties of polymer electrolyte based on poly-epsilon-caprolactone. Polym. Bull. 2015, 72 (1), 61-73.
Hazard Statements: H314-H318
Causes severe skin burns and eye damage. Causes serious eye damage.
Precautionary Statements: P260u-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a
Do not breathe dusts or mists. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.