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68703-51-5 - 5-O-tert-Butyldimethylsilyl-2,3-O-isopropylidene-alpha,beta-D-ribofuranose - L15986 - Alfa Aesar

L15986 5-O-tert-Butyldimethylsilyl-2,3-O-isopropylidene-alpha,beta-D-ribofuranose

CAS Number
68703-51-5
Synonyms

Size Price ($) Quantity Availability
250mg 41.00
1g 104.00
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5-O-tert-Butyldimethylsilyl-2,3-O-isopropylidene-alpha,beta-D-ribofuranose

MDL
MFCD01075716

Chemical Properties

Formula
C14H28O5Si
Formula Weight
304.46
Melting point
50-53°
Solubility
Soluble in dichloromethane and ethyl acetate.

Applications

5-O-tert-Butyldimethylsilyl-2,3-O-isopropylidene-α,β-D-ribofuranose is used as a starting material for the preparation of N-benzyl alfa-L-manno aminocyclopentitol , 4-deoxy-N-benzyl-alfa-L-manno aminocyclopentitol and N-benzyl 6,7-di-epi-trehalamine using stereoselective allylation. It is also used in oligosaccharides.

Notes

Incompatible with oxidizing agents.

Literature References

Ceballos, C.; Prata, C. A. H.; Giorgio, S.; Garzino, F.; Payet, D.; Barthélémy, P.; Grinstaff, M. W.; Camplo, M. Cationic Nucleoside Lipids Based on a 3-Nitropyrrole Universal Base for siRNA Delivery. Bioconjugate Chem. 2009, 20 (2), 193-196.

Suydam, I. T.; Strobel, S. A. Fluorine Substituted Adenosines As Probes of Nucleobase Protonation in Functional RNAs. J. Am. Chem. Soc. 2008, 130 (41), 13639-13648.

Other References

Harmonized Tariff Code
2932.19
TSCA
No

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    2,3-O-Isopropylidene-alpha,beta-D-ribofuranose

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