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3-Bromothiophene-2-carboxamide is used in Stille cross-coupling conditions were used to couple the resin-bound peptide.
Allix M. Sanders,; John D. Tovarab. Solid-phase Pd-catalysed cross-coupling methods for the construction of π-conjugated peptide nanomaterials. Supramolecular Chemistry. 2014 26 (3-4), 259-266.
Hazard Statements: H315-H319-H335
Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.
Precautionary Statements: P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.