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309-88-6 - Ishikawa's Reagent, 90+% - N,N-Diethyl-1,1,2,3,3,3-hexafluoropropylamine - L16738 - Alfa Aesar

L16738 Ishikawa's Reagent, 90+%

CAS Number
309-88-6
Synonyms
N,N-Diethyl-1,1,2,3,3,3-hexafluoropropylamine

Size Price ($) Quantity Availability
25g 65.92
100g 193.50
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Ishikawa's Reagent, 90+%

MDL
MFCD00054683

Chemical Properties

Formula
C7H11F6N
Formula Weight
223.16
Boiling Point
56-57°/58mm
Flash Point
14°(57°F)
Density
1.230
Refractive Index
1.3500

Literature References

A mixture of N,N-Diethyl-1,1,2,3,3,3-hexafluoropropylamine and N,N-Diethyl-1,2,3,3,3-pentafluoropropenamine, both of which are active fluorinating agents.

/n

For use in conversion, in ether or THF, of alcohols to alkyl fluorides, see: Bull. Chem. Soc. Jpn., 52, 3377 (1979); J. Fluorine Chem., 31, 135 (1986); 38, 243 (1988). Addition of NaF as a scavenger of the HF liberated in the reaction gives improved results: J. Fluorine Chem., 23, 383 (1983). Carboxylic acids are converted to acyl fluorides: Bull. Chem. Soc. Jpn., 52, 3377 (1979).

/n

GHS Hazard and Precautionary Statements

Hazard Statements: H225-H314-H318

Highly flammable liquid and vapour. Causes severe skin burns and eye damage. Causes serious eye damage.

Precautionary Statements: P210-P260-P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P310-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/physician. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Hazard Class
3
Packing Group
II
Harmonized Tariff Code
2921.19
TSCA
No

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