Cookies disclaimer

I agree Our site saves small pieces of text information (cookies) on your device in order to deliver better content and for statistical purposes. You can disable the usage of cookies by changing the settings of your browser. By browsing our website without changing the browser settings you grant us permission to store that information on your device.

L16751 Dimethyl fluoromalonate, 97%

CAS Number
344-14-9
Synonyms
Fluoromalonic acid dimethyl ester

Stock No. Size Price ($) Quantity Availability
L16751-03 1g 69.00
L16751-06 5g 243.00
Add to Cart Bulk/Specialty Print Quote View Item

Dimethyl fluoromalonate, 97%

MDL
MFCD00054680
EINECS
000-000-0

Chemical Properties

Formula
C5H7FO4
Formula Weight
150.11
Boiling Point
111-112°/45mm
Refractive Index
1.4032
Storage & Sensitivity
Ambient temperatures.

Literature References

Useful fluorinated building block. Reaction of the Na derivative with ɑ ß-unsaturated ketones or esters has been reported. At room temperature, a normal Michael reaction occurs, but on heating, reaction proceeds by a domino pathway providing a route to fluorinated trisubstituted alkenes: J. Org. Chem., 63, 7525 (1998):

/n

/n

GHS Hazard and Precautionary Statements

Hazard Statements: H314-H335

Causes severe skin burns and eye damage. May cause respiratory irritation.

Precautionary Statements: P260-P264b-P271-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P501c

Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Wash contaminated clothing before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
1768414
Hazard Class
8
Packing Group
II
Harmonized Tariff Code
2917.19
TSCA
No

Recommended

  • H59063

    2-Fluoro-N-phenylbenzamide, 97%
  • 38397

    Sodium chloride crystal optic rectangle, 38.5mm x 19.5mm x 4mm, unpolished
  • L17425

    3,5-Difluorobenzeneboronic acid, 97+%
  • L17020

    (1S,2S)-(+)-2-Benzyloxycyclohexylamine, ChiPros 99+%, ee 99%
  • 43278

    Boron nitride, Refractory Brushable Paint, BN 10%

Recently Viewed

Chemicals

Life Science

Metals & Materials

Catalysts

Analytical & Labware