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L16871 2,2,2-Trifluoroethyl acetate, 97%

CAS Number
406-95-1
Synonyms
Acetic acid 2,2,2-trifluoroethyl ester

Stock No. Size Price ($) Quantity Availability
L16871-14 25g 70.20
L16871-22 100g 186.00
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2,2,2-Trifluoroethyl acetate, 97%

MDL
MFCD00198018

Chemical Properties

Formula
C4H5F3O2
Formula Weight
142.08
Boiling Point
78°
Flash Point
11°(51°F)
Density
1.258
Refractive Index
1.3200
Storage & Sensitivity
Ambient temperatures.
Solubility
Soluble in water (16 g/L) (25°C)

Applications

2,2,2-Trifluoroethyl trifluoroacetate is used in the preparation of dimethyl (3,3,3-trifluoro-2,2-dihydroxypropyl)phosphonate

Notes

Store away from strong oxidizing agents. Keep container tightly closed. Store in cool, dry conditions in well sealed containers.

Literature References

Arnold C. Satterthwait.; William P. Jencks. Mechanism of the aminolysis of acetate esters. J. Am. Chem. Soc. 1974, 96, (22), 7018-7031.

William J. Hennen.; H. Marcel Sweers.; Yi Fong Wang.; Chi Huey Wong. Enzymes in carbohydrate synthesis. Lipase-catalyzed selective acylation and deacylation of furanose and pyranose derivatives. J. Org. Chem. 1988, 53, (21), 4939-4945.

GHS Hazard and Precautionary Statements

Hazard Statements: H225

Highly flammable liquid and vapour.

Precautionary Statements: P210-P233-P240-P241-P242-P243-P280-P303+P361+P353-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly closed. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
1757502
Hazard Class
3
Packing Group
II
Harmonized Tariff Code
2915.39
TSCA
No

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