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406-95-1 - 2,2,2-Trifluoroethyl acetate, 97% - Acetic acid 2,2,2-trifluoroethyl ester - L16871 - Alfa Aesar

L16871 2,2,2-Trifluoroethyl acetate, 97%

CAS Number
406-95-1
Synonyms
Acetic acid 2,2,2-trifluoroethyl ester

Size Price ($) Quantity Availability
25g 36.21
100g 129.90
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2,2,2-Trifluoroethyl acetate, 97%

MDL
MFCD00198018

Chemical Properties

Formula
C4H5F3O2
Formula Weight
142.08
Boiling Point
78°
Flash Point
11°(51°F)
Density
1.258
Refractive Index
1.3200
Solubility
Soluble in water (16 g/L) (25°C)

Applications

2,2,2-Trifluoroethyl trifluoroacetate is used in the preparation of dimethyl (3,3,3-trifluoro-2,2-dihydroxypropyl)phosphonate

Notes

Store away from strong oxidizing agents. Keep container tightly closed. Store in cool, dry conditions in well sealed containers.

Literature References

Arnold C. Satterthwait.; William P. Jencks. Mechanism of the aminolysis of acetate esters. J. Am. Chem. Soc. 1974, 96, (22), 7018-7031.

William J. Hennen.; H. Marcel Sweers.; Yi Fong Wang.; Chi Huey Wong. Enzymes in carbohydrate synthesis. Lipase-catalyzed selective acylation and deacylation of furanose and pyranose derivatives. J. Org. Chem. 1988, 53, (21), 4939-4945.

GHS Hazard and Precautionary Statements

Hazard Statements: H225

Highly flammable liquid and vapour.

Precautionary Statements: P210-P280-P240-P241-P233-P242-P243-P303+P361+P353-P403+P235-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Wear protective gloves/protective clothing/eye protection/face protection. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Keep container tightly closed. Use only non-sparking tools. Take precautionary measures against static discharge. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Store in a well-ventilated place. Keep cool. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
1757502
Hazard Class
3
Packing Group
II
Harmonized Tariff Code
2915.39
TSCA
No

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