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406-95-1 - 2,2,2-Trifluoroethyl acetate, 97% - Acetic acid 2,2,2-trifluoroethyl ester - L16871 - Alfa Aesar

L16871 2,2,2-Trifluoroethyl acetate, 97%

CAS Number
406-95-1
Synonyms
Acetic acid 2,2,2-trifluoroethyl ester

Size Price ($) Quantity Availability
25g 69.70
100g 186.00
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2,2,2-Trifluoroethyl acetate, 97%

MDL
MFCD00198018

Chemical Properties

Formula
C4H5F3O2
Formula Weight
142.08
Boiling Point
78°
Flash Point
11°(51°F)
Density
1.258
Refractive Index
1.3200
Solubility
Soluble in water (16 g/L) (25°C)

Applications

2,2,2-Trifluoroethyl trifluoroacetate is used in the preparation of dimethyl (3,3,3-trifluoro-2,2-dihydroxypropyl)phosphonate

Notes

Store away from strong oxidizing agents. Keep container tightly closed. Store in cool, dry conditions in well sealed containers.

Literature References

Arnold C. Satterthwait.; William P. Jencks. Mechanism of the aminolysis of acetate esters. J. Am. Chem. Soc. 1974, 96, (22), 7018-7031.

William J. Hennen.; H. Marcel Sweers.; Yi Fong Wang.; Chi Huey Wong. Enzymes in carbohydrate synthesis. Lipase-catalyzed selective acylation and deacylation of furanose and pyranose derivatives. J. Org. Chem. 1988, 53, (21), 4939-4945.

GHS Hazard and Precautionary Statements

Hazard Statements: H225

Highly flammable liquid and vapour.

Precautionary Statements: P260u-P201-P280a-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P310a-P405-P501a

Obtain special instructions before use. Wear protective gloves and eye/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
1757502
Hazard Class
3
Packing Group
II
Harmonized Tariff Code
2915.39
TSCA
No

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