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290-87-9 - 1,3,5-Triazine, 97% - s-Triazine - L16911 - Alfa Aesar

L16911 1,3,5-Triazine, 97%

CAS Number
290-87-9
Synonyms
s-Triazine

Size Price ($) Quantity Availability
1g 35.10
5g 127.00
25g 293.00
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1,3,5-Triazine, 97%

MDL
MFCD00006044
EINECS
206-028-1

Chemical Properties

Formula
C3H3N3
Formula Weight
81.08
Melting point
77-83° dec.
Boiling Point
114°
Density
1.380
Sensitivity
Moisture Sensitive
Solubility
Soluble in ethanol (50 mg/ml), and methanol (100 mg/ml).

Applications

1,3,5-Triazine is a useful replacement for HCN in the Gattermann reaction for the synthesis of aromatic aldehydes. It reacts with nucleophiles, e.g. amines, which is utilized in quinazoline synthesis.

Notes

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. It is hygroscopic in nature. Store under dry inert gas.

Literature References

N. G. McCormick.; J. H. Cornell.; A. M. Kaplan. Biodegradation of Hexahydro-1,3,5-Trinitro-1,3,5-Triazine. Appl. Environ. Microbiol.. 1981, 42 (5), 817-823.

Francis H. Case.; Emil Koft. The Synthesis of Certain Substituted 1,3,5-Triazines Containing the Ferroin Group. J. Am. Chem. Soc. 1959, 81 (4), 905-906.

Formylating agent: useful replacement for HCN in the Gattermann reaction for the synthesis of aromatic aldehydes: J. Am. Chem. Soc., 76, 290 (1954); Angew. Chem. Int. Ed., 6, 940 (1969); Arch. Pharm., 302, 828 (1969); 304, 362 (1971); with reactive substrates, formylation can be accomplished without a catalyst.

Also reacts with nucleophiles, e.g. amines, which has been utilized in a quinazoline synthesis: J. Chem. Soc. (C), 1282 (1969):

GHS Hazard and Precautionary Statements

Hazard Statements: H302-H315-H318-H335

Harmful if swallowed. Causes skin irritation. Causes serious eye damage. May cause respiratory irritation.

Precautionary Statements: P261-P280a-P305+P351+P338-P304+P340-P405-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
104790
Harmonized Tariff Code
2933.69
TSCA
No
RTECS
XY2957000

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