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23357-52-0 - (S)-(+)-1,2,3,4-Tetrahydro-1-naphthylamine, ChiPros® 99+%, ee 99% - (S)-1-Amino-1,2,3,4-tetrahydronaphthalene - L17022 - Alfa Aesar

L17022 (S)-(+)-1,2,3,4-Tetrahydro-1-naphthylamine, ChiPros® 99+%, ee 99%

CAS Number
23357-52-0
Synonyms
(S)-1-Amino-1,2,3,4-tetrahydronaphthalene

Size Price ($) Quantity Availability
1g 29.80
5g 73.90
25g 250.00
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(S)-(+)-1,2,3,4-Tetrahydro-1-naphthylamine, ChiPros® 99+%, ee 99%

MDL
MFCD00671630
EINECS
000-000-0

Chemical Properties

Formula
C10H13N
Formula Weight
147.22
Boiling Point
118-120°/8mm
Flash Point
>110°(230°F)
Density
1.035
Refractive Index
1.5645
Sensitivity
Air Sensitive
Solubility
Soluble in water.

Applications

(S)-(+)-1,2,3,4-Tetrahydro-1-naphthylamine is used as a chiral amine derivative used in studies of real-time chiral discrimination of enantiomers as well as in studies of kinetic resolution of chiral amines with ω-transaminase using an enzyme-membrane reactor.

Notes

Air Sensitive. Keep container tightly closed. Store in cool, dry conditions in well sealed containers.

Literature References

Yunmi Lee.; Amir H. Hoveyda. Efficient Boron-Copper Additions to Aryl-Substituted Alkenes Promoted by NHC-Based Catalysts. Enantioselective Cu-Catalyzed Hydroboration Reactions. J. Am. Chem. Soc. 2009, 131 (9), 3160-3161.

Cathleen M. Crudden.; Yonek B. Hleba.; Austin C. Chen. Regio- and Enantiocontrol in the Room-Temperature Hydroboration of Vinyl Arenes with Pinacol Borane. J. Am. Chem. Soc. 2004, 126 (30), 9200-9201.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P280-P305+P351+P338-P304+P340-P362-P312-P321-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Specific treatment (see label). Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
2360279
Harmonized Tariff Code
2921.45
TSCA
No

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