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3082-62-0 - (S)-(-)-1-(2-Naphthyl)ethylamine, ChiPros 99+%, ee 99+% - L17024 - Alfa Aesar

L17024 (S)-(-)-1-(2-Naphthyl)ethylamine, ChiPros 99+%, ee 99+%

CAS Number
3082-62-0
Synonyms

Size Price ($) Quantity Availability
1g 40.20
5g 122.00
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(S)-(-)-1-(2-Naphthyl)ethylamine, ChiPros 99+%, ee 99+%

MDL
MFCD00085366

Chemical Properties

Formula
C12H13N
Formula Weight
171.24
Melting point
48-52°
Boiling Point
90°/0.15mm
Sensitivity
Air Sensitive
Solubility
Insoluble in water.

Applications

(S)-(-)-1-(2-Naphthyl)ethylamine is used in asymmetric synthesis. It is also used in the preparation of thiourea compounds using chiral amine, which is used as a bifunctional catalyst for the Strecker and nitro-Michael reactions. Further, it acts as a chiral building block and chiral resolution reagent.

Notes

Incompatible with strong oxidizing agents. Sensitive to carbon dioxide.

Literature References

Shcherbakova, E. G.; Minami, T.; Brega, V.; James, T. D.; Anzenbacher, P. Determination of Enantiomeric Excess in Amine Derivatives with Molecular Self-Assemblies. Angew. Chem. Int. Ed. 2015, 54 (24), 7130-7133.

Polindara-García, L. A.; Montesinos-Miguel, D.; Vazquez, A. An efficient microwave-assisted synthesis of cotinine and iso-cotinine analogs from an Ugi-4CR approach. Org. Biomol. Chem. 2015, 13 (34), 9065-9071.

GHS Hazard and Precautionary Statements

Hazard Statements: H301-H311-H314-H318

Toxic if swallowed. Toxic in contact with skin. Causes severe skin burns and eye damage. Causes serious eye damage.

Precautionary Statements: P260-P280-P301+P310-P303+P361+P353-P305+P351+P338-P361-P301+P330+P331-P304+P340-P405-P501a

Do not breathe dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
3195949
Hazard Class
8
Packing Group
III
Harmonized Tariff Code
2921.49
TSCA
No

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