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1663-39-4 - tert-Butyl acrylate, 99%, stab. with 15ppm 4-methoxyphenol - Acrylic acid tert-butyl ester - L17169 - Alfa Aesar

L17169 tert-Butyl acrylate, 99%, stab. with 15ppm 4-methoxyphenol

CAS Number
1663-39-4
Synonyms
Acrylic acid tert-butyl ester

Size Price ($) Quantity Availability
100ml 21.22
500ml 43.67
1000ml 74.57
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tert-Butyl acrylate, 99%, stab. with 15ppm 4-methoxyphenol

MDL
MFCD00008809
EINECS
216-768-7

Chemical Properties

Formula
C7H12O2
Formula Weight
128.17
Melting point
ca -69°
Boiling Point
121°
Flash Point
11°(52°F)
Density
0.883
Refractive Index
1.4110
Solubility
Slightly miscible with water.

Applications

tert-Butyl acrylate is a monomer used in the production of poly(tert-butyl acrylate) polymers, poly(acrylic acid) polyelectrolyte brushes and 3-(3-methyl-but-3-enyloxy)-propionic acid tert-butyl ester. It is also used in paints, coatings, high polymer paper conditioner, nursing polymer products and carbonyl reforming polyolefin. Further, it serves as an important raw material in organic synthesis.

Notes

Incompatible with strong oxidizing agents.

Literature References

Kohsaka, Y.; Ishihara, S.; Kitayama, T. Termination of Living Anionic Polymerization of Butyl Acrylate with α-(Chloromethyl) acrylate for End-Functionalization and Application to the Evaluation of Monomer Reactivity. Macromol. Chem. Phys. 2015, 216 (14), 1534-1539.

Li, W.; Kanyo, I.; Kuo, C. H.; Thanneeru, S.; He, J. pH-programmable self-assembly of plasmonic nanoparticles: hydrophobic interaction versus electrostatic repulsion. Nanoscale 2015, 7 (3), 956-964.

GHS Hazard and Precautionary Statements

Hazard Statements: H225-H302-H312-H332-H315-H317-H335-H411

Highly flammable liquid and vapour. Harmful if swallowed. Harmful in contact with skin. Harmful if inhaled. Causes skin irritation. May cause an allergic skin reaction. May cause respiratory irritation. Toxic to aquatic life with long lasting effects.

Precautionary Statements: P210-P261-P273-P280-P240-P303+P361+P353-P304+P340-P362-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Avoid breathing dust/fume/gas/mist/vapours/spray. Avoid release to the environment. Wear protective gloves/protective clothing/eye protection/face protection. Ground/bond container and receiving equipment. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
1742329
Hazard Class
3
Packing Group
II
Harmonized Tariff Code
2916.12
TSCA
Yes

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