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L17279 3-Bromo-N,N-dimethylaniline, 97%

CAS Number
16518-62-0
Synonyms

Stock No. Size Price ($) Quantity Availability
L17279-06 5g 65.80
L17279-14 25g 256.00
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3-Bromo-N,N-dimethylaniline, 97%

MDL
MFCD00045020
EINECS
000-000-0

Chemical Properties

Formula
C8H10BrN
Formula Weight
200.08
Melting point
11°
Boiling Point
126°/14mm
Density
1.365
Refractive Index
1.6015
Storage & Sensitivity
Ambient temperatures.
Solubility
Miscible with chloroform, dichloromethane and methanol.

Applications

3-Bromo-N,N-dimethylaniline is involved in fluorination using metal fluoride in the presence of 2-(di-1-adamantylphosphino)-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl (AdBrettPhos)-based Pd precatalyst, used to prepare 3-fluoro-N,N- dimethylaniline.

Notes

Light sensitive. Store in cool place. Incompatible with strong oxidizing agents and strong acids.

Literature References

Sursvakova, V. V.; Burmakina, G. V.; Rubaylo, A. I. Palladium-Catalyzed Oxidative Carbonylation of Aromatic C-H Bonds of N-Alkylanilines with CO and Alcohols for the Synthesis of o-Aminobenzoates. J. Org. Chem. 2015, 80 (2), 1258-1263.

Ding, Q.; Zhou, X.; Pu, S.; Cao, B. Rhodium-catalyzed ortho-selective C-H halogenation of 2-arylbenzo[d]thiazoles using N-halosuccinimides as halogen sources. Tetrahedron 2015, 71 (16), 2376-2381.

GHS Hazard and Precautionary Statements

Hazard Statements: H302+H312+H332-H315-H319

Harmful if swallowed. Harmful in contact with skin. Harmful if inhaled. Causes skin irritation. Causes serious eye irritation.

Precautionary Statements: P261-P264b-P270-P271-P280-P301+P312-P302+P352-P304+P340-P305+P351+P338-P312-P330-P332+P313-P337+P313-P362-P501c

Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Rinse mouth. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
2079908
Harmonized Tariff Code
2921.42
TSCA
No

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