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AccuFluor is a registered trademark of AlliedSignal Inc./n
Versatile, reactive electrophilic fluorinating agent which can be used in water or organic solvents. A variety of substrates such as ketones: Tetrahedron Lett., 37, 3591 (1996), aromatics and enol ethers or enol esters, including steroidal derivatives, can be fluorinated successfully under mild conditions: Tetrahedron Lett., 40, 2673 (1999):/n
Active methylene compounds (ß-diketonesandß-keto esters) are fluorinated in good yield in the presence of zinc chloride and imidazole or collidine. In the presence of water or alcohols, alkenes undergo hydroxy- or alkoxyfluorination to give fluorohydrin derivatives: Tetrahedron Lett., 36, 6769 (1995); 40, 2673 (1999)./n
Hazard Statements: H302-H318-H317-H373
Harmful if swallowed. Causes serious eye damage. May cause an allergic skin reaction. May cause damage to organs through prolonged or repeated exposure.
Precautionary Statements: P260-P280a-P305+P351+P338-P310a-P301+P312a-P501a
Do not breathe dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Dispose of contents/container in accordance with local/regional/national/international regulations.