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32779-36-5 - 5-Bromo-2-chloropyrimidine, 98+% - L18360 - Alfa Aesar

L18360 5-Bromo-2-chloropyrimidine, 98+%

CAS Number
32779-36-5
Synonyms

Size Price ($) Quantity Availability
1g 28.20
5g 102.00
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5-Bromo-2-chloropyrimidine, 98+%

MDL
MFCD00483232
EINECS
000-000-0

Chemical Properties

Formula
C4H2BrClN2
Formula Weight
193.43
Melting point
77-80°
Boiling Point
95°/15mm
Solubility
Insoluble in water. Slightly soluble in DMSO and methanol.

Applications

It is applied as a pharmaceutical intermediate, in the synthesis of pharmaceutical goods such as inhibitors. It is also employed in the cross-coupling reactions of indium organometallics with 2,5-dihalopyrimidines.

Notes

Store away from oxidizing agents. Keep the container tightly closed and place it in a cool, dry and well ventilated condition.

Literature References

John W. Goodby, et al. 5-Bromo-2-iodopyrimidine: a novel, useful intermediate in selective palladium-catalyzed cross-coupling reactions for efficient convergent syntheses.Chem. Commun.,1996,(24), 2719-2720.

Ángeles Mosquera, et al. Cross-Coupling Reactions of Indium Organometallics with 2,5-Dihalopyrimidines: Synthesis of Hyrtinadine A.Org. Lett.,2008,10(17), 3745-3748.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P280-P305+P351+P338-P304+P340-P362-P312-P321-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Specific treatment (see label). Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
507955
Harmonized Tariff Code
2933.59
TSCA
No

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