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Extremely active catalyst for the reaction of carboxylic acids with primary and secondary amines to give the corresponding amides in very high yields: J. Org. Chem., 61, 4196 (1996). Also useful in the one-pot synthesis of acyl azides from carboxylic acids and NaN3: Tetrahedron Lett., 43, 9715 (2002). Mediates the mild, one-pot reduction of carboxylic acids to alcohols with NaBH4: Tetrahedron Lett., 44, 3427 (2003)./n
For other boronic acid chemistry, see Appendix 5./n
Hazard Statements: H315-H319-H335
Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.
Precautionary Statements: P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.