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2-Bromobenzeneboronic acid is used to promote greener amidations of carboxylic acids and amines in catalytic amounts. This technology avoids the requirement of preactivation of the carboxylic acid or use of coupling reagents.
Munawar Hussain.; Nguyen Thai Hung.; Rasheed Ahmed Khera.; Alexander Villinger.; Peter Langer. Site-selective Suzuki-Miyaura reactions of 2,3-dibromo-1H-inden-1-one. Tetrahedron Letters. 2011, 52 (2), 184-187.
Mahdy M. Elmahdy.; George Floudas Prof.; Luke Oldridge.; Andrew C. Grimsdale Dr.; Klaus Müllen Prof. Self-Assembly and Molecular Dynamics of Oligoindenofluorenes. ChemPhysChem. 2006, 7 (7), 1431-1441.
Hazard Statements: H315-H319-H335
Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.
Precautionary Statements: P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.