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14898-80-7 - (S)-(+)-4-Methyl-2-pentanol, 99% - L18882 - Alfa Aesar

L18882 (S)-(+)-4-Methyl-2-pentanol, 99%

CAS Number
14898-80-7
Synonyms

Size Price ($) Quantity Availability
250mg 58.80
1g 189.00
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(S)-(+)-4-Methyl-2-pentanol, 99%

MDL
MFCD03093078

Chemical Properties

Formula
C6H14O
Formula Weight
102.18
Boiling Point
130-131°
Flash Point
41°(105°F)
Density
0.802
Refractive Index
1.4110
Solubility
Slightly soluble in water. Soluble in alcohol.

Applications

It is employed in the reaction of 2-methoxyethyl acetals with allylsilanes in the presence of titanium tetrachloride: regioselective carbon-oxygen bond cleavage of the unsymmetrical acetals.

Notes

Store away from oxidizing agents. Keep the container tightly closed and place it in a cool, dry and well ventilated condition. Keep ignition sources away. Protect from electrostatic charges.

Literature References

Mao-Ya Yin, et al. Asymmetric hydrogenation of ketones catalyzed by a silica-supported chitosan-palladium complex.J. Mol. Catal. A: Chem.,1999,147(1-2), 93-98.

Philip E. Sonnet, et al. Kinetic resolutions of aliphatic alcohols with a fungal lipase from Mucor miehei.J. Org. Chem.,1987,52(15), 3477-3479.

GHS Hazard and Precautionary Statements

Hazard Statements: H226-H335-H303-H313

Flammable liquid and vapour. May cause respiratory irritation. May be harmful if swallowed. May be harmful in contact with skin.

Precautionary Statements: P262

Do not get in eyes, on skin, or on clothing.

Other References

Beilstein
1718991
Hazard Class
3
Packing Group
III
Harmonized Tariff Code
2905.19
TSCA
No

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    (R)-(-)-4-Methyl-2-pentanol, 99%

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