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L18882 (S)-(+)-4-Methyl-2-pentanol, 99%

CAS Number
14898-80-7
Synonyms

Stock No. Size Price ($) Quantity Availability
L18882-MD 250mg 59.20
L18882-03 1g 189.00
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(S)-(+)-4-Methyl-2-pentanol, 99%

MDL
MFCD03093078

Chemical Properties

Formula
C6H14O
Formula Weight
102.18
Boiling Point
130-131°
Flash Point
41°(105°F)
Density
0.802
Refractive Index
1.4110
Storage & Sensitivity
Ambient temperatures.
Solubility
Slightly soluble in water. Soluble in alcohol.

Applications

It is employed in the reaction of 2-methoxyethyl acetals with allylsilanes in the presence of titanium tetrachloride: regioselective carbon-oxygen bond cleavage of the unsymmetrical acetals.

Notes

Store away from oxidizing agents. Keep the container tightly closed and place it in a cool, dry and well ventilated condition. Keep ignition sources away. Protect from electrostatic charges.

Literature References

Mao-Ya Yin, et al. Asymmetric hydrogenation of ketones catalyzed by a silica-supported chitosan-palladium complex.J. Mol. Catal. A: Chem.,1999,147(1-2), 93-98.

Philip E. Sonnet, et al. Kinetic resolutions of aliphatic alcohols with a fungal lipase from Mucor miehei.J. Org. Chem.,1987,52(15), 3477-3479.

GHS Hazard and Precautionary Statements

Hazard Statements: H226-H335

Flammable liquid and vapour. May cause respiratory irritation.

Precautionary Statements: P210-P233-P235-P240-P241-P242-P243-P271-P280-P303+P361+P353-P304+P340-P312-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly closed. Keep cool. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
1718991
Hazard Class
3
Packing Group
III
Harmonized Tariff Code
2905.19
TSCA
No

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    (R)-(-)-4-Methyl-2-pentanol, 99%

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