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2483-57-0 - Methyl nitroacetate, 98% - Nitroacetic acid methyl ester - L18950 - Alfa Aesar

L18950 Methyl nitroacetate, 98%

CAS Number
2483-57-0
Synonyms
Nitroacetic acid methyl ester

Size Price ($) Quantity Availability
2g 58.00
10g 222.00
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Methyl nitroacetate, 98%

MDL
MFCD00075480
EINECS
219-622-0

Chemical Properties

Formula
C3H5NO4
Formula Weight
119.08
Boiling Point
195-198°
Flash Point
105°(221°F)
Density
1.294
Refractive Index
1.4260
Sensitivity
Light Sensitive
Solubility
Miscible with ethanol, ether and most organic solvents.

Applications

Methyl nitroacetate is used in the synthesis of aromatic and heteroaromatic linear (E)-alfa-nitro-arylpentenoates. It is also used to prepare phenyliodonium ylide. Further, it is utilized in the highly enantioselective and diastereoselective copper(I)-catalyzed cyclopropanation of alkenes. In addition to this, it is employed in the production of methyl (Z)-2-nitro-3-(4-nitrophenyl)-2-propenoate through reaction with 4-nitrobenzylideneaniline.

Notes

Light sensitive. Incompatible withstrong bases.

Literature References

Hoffmann, R. C.; Schneider, J. J. Synergistic and Antagonistic Ligand Effects in the Transformation of Silver Compounds of Keto- and Cyano-Functionalised Oximates and Nitronates: A Systematic Study Using Thermal Analysis. Eur. J. Inorg. Chem. 2015, 2015 (25), 4254-4259.

Afreh, I.; Wujcik, E. K.; Blasdel, N.; Sauer, B.; Kaya, S.; Duirk, S.; Monty, C. N. Detection of halogenated organics by their inhibitory action in a catalytic reaction between dimethyl acetylenedicarboxylate and 2-methyl-4-nitroaniline. J. Anal. Chem. 2015, 70 (7), 825-830.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335-H303

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation. May be harmful if swallowed.

Precautionary Statements: P280g-P305+P351+P338

Wear protective gloves. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Other References

Beilstein
1758670
Harmonized Tariff Code
2915.90
TSCA
No
RTECS
AJ1093000

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