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18422-53-2 - D-Epoxone, 98% - 1,2:4,5-Di-O-isopropylidene-beta-D-erythro-2,3-hexodiulo-2,6-pyranose - L18989 - Alfa Aesar

L18989 D-Epoxone, 98%

CAS Number
18422-53-2
Synonyms
1,2:4,5-Di-O-isopropylidene-beta-D-erythro-2,3-hexodiulo-2,6-pyranose

Size Price ($) Quantity Availability
1g 39.04
5g 128.75
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D-Epoxone, 98%

MDL
MFCD00063383
EINECS
000-000-0

Chemical Properties

Formula
C12H18O6
Formula Weight
258.27
Melting point
101-103°
Solubility
Soluble in chloroform and methanol.

Applications

D-Epoxone is a chemical reagent used for enantioselective epoxidation of alkenes. It is involved in the synthesis of Irciniastatin (A and B), which are used as antitumor compounds. It is used as cytotoxic secondary metabolite.

Notes

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Incompatible with strong oxidizing agents.

Literature References

Tran, A. T.; Luo, B.; Jagadeesh, Y.; Auberger, N.; Désiré, J.; Nakagawa, S.; Kato, A.; Zhang, Y.; Blériot, Y.; Sollogoub, M. Synthesis of pyrrolidine-based analogues of 2-acetamidosugars as N-acetyl-d-glucosaminidase inhibitors. Carbohydr. Res. 2015, 409, 56-62.

Ren, X-D.; Zhao, N.; Xu, S.; Lü, H-N.; Ma, S-G.; Liu, Y-B.; Li, Y.; Qu, J.; Yu, S-S. Total synthesis of illicidione A and illihendione A. Tetrahedron 2015, 71 (29), 4821-4829.

Other References

Beilstein
1319073
Harmonized Tariff Code
2932.99
TSCA
No

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