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4187-56-8 - (S)-(-)-1-(4-Chlorophenyl)ethylamine, ChiPros® 97%, ee 98% - (S)-4-Chloro-alpha-methylbenzylamine - ClophaS - L19052 - Alfa Aesar

L19052 (S)-(-)-1-(4-Chlorophenyl)ethylamine, ChiPros® 97%, ee 98%

CAS Number
4187-56-8
Synonyms
(S)-4-Chloro-alpha-methylbenzylamine
ClophaS

Size Price ($) Quantity Availability
5g 99.70
25g 368.00
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(S)-(-)-1-(4-Chlorophenyl)ethylamine, ChiPros® 97%, ee 98%

MDL
MFCD00671640

Chemical Properties

Formula
C8H10ClN
Formula Weight
155.63
Boiling Point
232°
Flash Point
115°(239°F)
Density
1.110
Refractive Index
1.5418
Sensitivity
Air Sensitive
Solubility
Soluble in water at 25°C 11 g/L.

Applications

It is used as a substrate in palladium catalysts on alkaline-earth supports for racemization and dynamic kinetic resolution of benzylic amines.

Notes

Air sensitive. Store away from acids, air, acid chlorides, acid anhydrides and oxidizing agents. Keep the container tightly closed and place it in a cool, dry and well ventilated condition. Store under inert gas.

Literature References

R. Jansen, et al. Structural Similarity and Its Surprises:? Endothelin Receptor Antagonists - Process Research and Development Report.Org. Proc. Res. Dev.,2001,5(1), 16-22.

Sandra Reemers, et al. Cobalt complexes derived from chiral quasi-racemic ligands as building blocks for binary crystals.Inorg. Chem. Commun.,2002,5(10), 829-831.

GHS Hazard and Precautionary Statements

Hazard Statements: H302-H330-H315-H318-H317

Harmful if swallowed. Fatal if inhaled. Causes skin irritation. Causes serious eye damage. May cause an allergic skin reaction.

Precautionary Statements: P304+P340-P305+P351+P338-P320-P330-P405-P501a

IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Specific treatment is urgent (see label). Rinse mouth. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
2412316
Hazard Class
6.1
Packing Group
11
Harmonized Tariff Code
2921.49
TSCA
No

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