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L19086 1-n-Butyl-3-methylimidazolium hexafluorophosphate, 98+%

CAS Number
174501-64-5
Synonyms
BMIMPF6

Stock No. Size Price ($) Quantity Availability
L19086-06 5g 32.80
L19086-14 25g 90.20
L19086-22 100g 266.00
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1-n-Butyl-3-methylimidazolium hexafluorophosphate, 98+%

MDL
MFCD03093295
EINECS
000-000-0

Chemical Properties

Formula
C8H15F6N2P
Formula Weight
284.19
Melting point
8-10°
Boiling Point
>350°
Density
1.365
Refractive Index
1.4115
Storage & Sensitivity
Hygroscopic. Ambient temperatures.
Solubility
Miscible with dichloromethane, chloroform, ethyl acetate. Immiscible with water, diethyl ether and hexane.

Applications

1-n-Butyl-3-methylimidazolium hexafluorophosphate is used as a solvent in headspace gas chromatography and countercurrent chromatography, as mobile and stationary phases. It is widely used in organic synthesis, extraction technologies, electochemistry and biphasic organometallic catalysis.

Notes

Hygroscopic. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Incompatible with strong oxidizing agents.

Literature References

Soni, S. K.; Sarkar, S.; Mirzadeh , N.; Selvakannan , P. R.; Bhargava, S. K. Self-Assembled Functional Nanostructure of Plasmid DNA with Ionic Liquid [Bmim][PF6]: Enhanced Efficiency in Bacterial Gene Transformation. Langmuir. 2015, 31 (16), 4722-4732.

Zhang, Y.; Zhang, T.; Gan, P.; Li, H.; Zhang, M.; Jin, K.; Tang, S. Solubility of Isobutane in Ionic Liquids [BMIm][PF6], [BMIm][BF4], and [BMIm][Tf2N]. J. Chem. Eng. Data. 2015, 60 (6), 1706-1714.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P337+P313-P362-P501c

Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Merck
14,1581
Harmonized Tariff Code
2933.29
TSCA
No

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