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Selective oxidant, less acidic than PCC (Pyridinium chlorochromate, A11752) for high-yield conversion of primary and secondary alcohols to carbonyl compounds: Synthesis, 588 (1982). Enables selective oxidation of a secondary alcohol in the presence of the TBDMS ether of a primary alcohol, where PCC causes cleavage: Bull. Chem. Soc. Jpn., 57, 2019 (1984)./n
Hazard Statements: H272-H317
May intensify fire; oxidizer. May cause an allergic skin reaction.
Precautionary Statements: P210-P220-P221-P272-P280-P302+P352-P333+P313-P363-P370+P380+P375-P372-P380-P501c
Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep/Store away from clothing/combustible materials. Take any precaution to avoid mixing with combustibles. Contaminated work clothing should not be allowed out of the workplace. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. If skin irritation or rash occurs: Get medical advice/attention. Wash contaminated clothing before reuse. In case of fire: Evacuate area. Fight fire remotely due to the risk of explosion. Explosion risk in case of fire. Dispose of contents/ container to an approved waste disposal plant