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L19321 2-Bromo-4-fluorobenzoic acid, 98%

CAS Number
1006-41-3
Synonyms

Stock No. Size Price ($) Quantity Availability
L19321-03 1g 19.30
L19321-06 5g 46.50
L19321-14 25g 134.00
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2-Bromo-4-fluorobenzoic acid, 98%

MDL
MFCD00055370
EINECS
000-000-0

Chemical Properties

Formula
C7H4BrFO2
Formula Weight
219.01
Melting point
167-169°
Storage & Sensitivity
Ambient temperatures.
Solubility
Soluble in water and methanol.

Applications

2-Bromo-4-fluorobenzoic acid is used in the synthesis of 3-fluoro-8-(methylthio)dibenzo[b,f]thiepin-10(11H)-one, 2-fluoro-8-(methylthio)dibenzo[b,f]thiepin-10(11H)-one, 2-((2-carboxy-5-fluorophenyl)amino)-3-methoxybenzoic acid and 2-bromo-4-fluorobenzamide. It is also used in the preparation of boron-containing anti-fungal agents, in the treatment of onychomycosis.

Notes

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Incompatible with oxidizing agents.

Literature References

Lauren R Donaldson.; Stephen Wallace.; David Haigh.; E Elizabeth Patton.; Alison N Hulme. Rapid synthesis and zebrafish evaluation of a phenanthridine-based small molecule library. Organic & Biomolecular Chemistry. 2011, 9 (7), 2233-2239.

Christian Wolf.; Shuanglong Liu.; Xuefeng Mei.; Adam T August.; Michael D Casimir. Regioselective copper-catalyzed amination of bromobenzoic acids using aliphatic and aromatic amines. Journal of Organic Chemistry. 2006, 71 (8), 3270-3273.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P362-P501c

Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
2614292
Harmonized Tariff Code
2916.39
TSCA
No

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