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Aza-dienophile; the cycloaddition products can be debenzylated by hydrogenolysis: J. Am. Chem. Soc., 109, 285 (1987); 110, 5229 (1988); 111, 2995 (1989). Compare Di-tert-butyl azodicarboxylate, L00294, Diethyl azodicarboxylate, L19348, and Diisopropyl azodicarboxylate, L10386. Effects enantioselective ɑ-amination of aldehydes, mediated by L-Proline, A10199: J. Am. Chem. Soc., 124, 5656 (2002):/n
For the formation of functionalized ß-amino alcohols by the three-component asymmetric assembly with an aldehyde and a ketone, see: Org. Lett, 5, 1685 (2003)./n
Hazard Statements: H315-H319-H335
Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.
Precautionary Statements: P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.