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133407-38-2 - (R)-(+)-N-Methoxymethyl-N-(trimethylsilyl)methyl-1-phenylethylamine, tech. 85% - L19413 - Alfa Aesar

L19413 (R)-(+)-N-Methoxymethyl-N-(trimethylsilyl)methyl-1-phenylethylamine, tech. 85%

CAS Number
133407-38-2
Synonyms

Size Price ($) Quantity Availability
1g 63.36
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(R)-(+)-N-Methoxymethyl-N-(trimethylsilyl)methyl-1-phenylethylamine, tech. 85%

MDL
MFCD06798959

Chemical Properties

Formula
C14H25NOSi
Formula Weight
251.45
Boiling Point
82-84°/0.2mm
Density
0.926
Refractive Index
1.4930
Sensitivity
Moisture Sensitive
Solubility
Not miscible or difficult to mix in water.

Applications

(R)-(+)-N-Methoxymethyl-N-(trimethylsilyl)methyl-1-phenylethylamine ligand is commonly used in the synthesis of organometallic catalysts and for many applications, such as asymmetric hydrogenation, asymmetric hydroboration, coupling reactions, addition reactions and reductions reactions.

Notes

Store under inert gas. It is sensitive to moisture. Store in a cool, dry conditions in well sealed containers. Incompatible with oxidizing agents.

Literature References

Andrew H. Fray.; A. I. Meyers. Single and Double Diastereoselection in Azomethine Ylide Cycloaddition Reactions with Unsaturated Chiral Bicyclic Lactams. J. Org. Chem. 1996, 61 (10), 3362-3374.

The azomethine ylide, from the reaction with TFA in DCM, showed high facial selectivity in additions to chiral unsaturated bicyclic lactams: J. Org. Chem., 61, 3362 (1996).

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P280a-P305+P351+P338-P304+P340-P405-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
4745464
Harmonized Tariff Code
2931.90
TSCA
No

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