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(R)-(+)-N-Methoxymethyl-N-(trimethylsilyl)methyl-1-phenylethylamine ligand is commonly used in the synthesis of organometallic catalysts and for many applications, such as asymmetric hydrogenation, asymmetric hydroboration, coupling reactions, addition reactions and reductions reactions.
Andrew H. Fray.; A. I. Meyers. Single and Double Diastereoselection in Azomethine Ylide Cycloaddition Reactions with Unsaturated Chiral Bicyclic Lactams. J. Org. Chem. 1996, 61 (10), 3362-3374.
The azomethine ylide, from the reaction with TFA in DCM, showed high facial selectivity in additions to chiral unsaturated bicyclic lactams: J. Org. Chem., 61, 3362 (1996).
Hazard Statements: H315-H319-H335
Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.
Precautionary Statements: P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.