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100243-39-8 - (S)-(-)-3-Hydroxypyrrolidine, 99%, ee 99% - (S)-(-)-3-Pyrrolidinol - L19498 - Alfa Aesar

L19498 (S)-(-)-3-Hydroxypyrrolidine, 99%, ee 99%

CAS Number
100243-39-8
Synonyms
(S)-(-)-3-Pyrrolidinol

Size Price ($) Quantity Availability
250mg 54.50
1g 144.00
5g 554.00
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(S)-(-)-3-Hydroxypyrrolidine, 99%, ee 99%

MDL
MFCD00192426

Chemical Properties

Formula
C4H9NO
Formula Weight
87.12
Melting point
15°
Boiling Point
108-110°/8mm
Flash Point
>110°(230°F)
Density
1.048
Refractive Index
1.4900
Sensitivity
Air Sensitive & Hygroscopic
Solubility
Fully miscible in water.

Applications

(S)-(-)-3-Hydroxypyrrolidine is an important raw material and intermediate used in organic synthesis, pharmaceuticals agrochemicals and dyestuff fields.

Notes

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Incompatible with oxidizing agents. It is hygroscopic and sensitive to air.

Literature References

Zhi Li, Hans-Jürgen Feiten, Jan B van Beilen, Wouter Duetz, Bernard Witholtt. Preparation of optically active N-benzyl-3-hydroxypyrrolidine by enzymatic hydroxylation. Tetrahedron: Asymmetry. 1999, 10 (7), 1323-1333.

Zhi Li.; Hans-Jürgen Feiten.; Dongliang Chang.; Wouter A. Duetz.; Jan B. van Beilen.; Bernard Witholt. Preparation of (R)- and (S)-N-Protected 3-Hydroxypyrrolidines by Hydroxylation with Sphingomonas sp. HXN-200, a Highly Active, Regio- and Stereoselective, and Easy to Handle Biocatalyst. J. Org. Chem. 2001, 66 (25), 8424-8430.

Product of Toray Industries, Inc.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P280-P305+P351+P338-P304+P340-P362-P312-P321-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Specific treatment (see label). Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
4652606
Harmonized Tariff Code
2933.99
TSCA
No

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    (R)-(+)-3-Hydroxypyrrolidine, 99%, ee 99%

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