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2799-21-5 - (R)-(+)-3-Hydroxypyrrolidine, 99%, ee 99% - (R)-(+)-3-Pyrrolidinol - L19499 - Alfa Aesar

L19499 (R)-(+)-3-Hydroxypyrrolidine, 99%, ee 99%

CAS Number
2799-21-5
Synonyms
(R)-(+)-3-Pyrrolidinol

Size Price ($) Quantity Availability
1g 57.51
5g 162.38
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(R)-(+)-3-Hydroxypyrrolidine, 99%, ee 99%

MDL
MFCD00145220

Chemical Properties

Formula
C4H9NO
Formula Weight
87.12
Melting point
15°
Boiling Point
108-110°/8mm
Flash Point
>110°(230°F)
Density
1.048
Refractive Index
1.4900
Sensitivity
Air Sensitive & Hygroscopic
Solubility
Soluble in water and methanol.

Applications

(R)-(+)-3-Hydroxypyrrolidine is used in the enantioselective addition of diethylzinc to aromatic aldehydes leading to optically active secondary alcohols. Also used to prepare-κ-opioid receptor agonists.

Notes

Store under inert gas. It is sensitive to moisture. Store in a cool, dry conditions in well sealed containers. It is hygroscopic and sensitive to air. Incompatible with oxidizing agents.

Literature References

A Naylor.; D B Judd.; D I Scopes.; A G Hayes.; P J Birch. 4-[(Alkylamino)methyl]furo[3,2-c]pyridines: a new series of selective kappa-receptor agonists. Journal of Medicinal Chemistry. 1994, 37 (14), 2138-2144.

Mitsunori Hashimoto.; Yutaka Eda.; Yasutomo Osanai.; Toshiaki Iwai.; Seiichi Aoki. A Novel Decarboxylation of α-amino acids. A Facile Method of Decarboxylation by the use of 2-Cyclohexen-1-one as a Catalyst. Chemistry Letters. 1986, 15 (6), 893-896.

Product of Toray Industries, Inc.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319

Causes skin irritation. Causes serious eye irritation.

Precautionary Statements: P280-P264-P305+P351+P338-P362-P321-P332+P313-P337+P313-P302+P352

Wear protective gloves/protective clothing/eye protection/face protection. Wash thoroughly after handling. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Take off contaminated clothing and wash before reuse. Specific treatment (see label). If skin irritation occurs: Get medical advice/attention. If eye irritation persists: IF ON SKIN: Wash with plenty of soap and water.

Other References

Beilstein
5376132
Harmonized Tariff Code
2933.99
TSCA
No

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