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34160-40-2 - 6-Bromopyridine-2-carboxaldehyde, 97% - L19518 - Alfa Aesar

L19518 6-Bromopyridine-2-carboxaldehyde, 97%

CAS Number
34160-40-2
Synonyms

Size Price ($) Quantity Availability
1g 35.20
5g 107.00
25g 431.00
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6-Bromopyridine-2-carboxaldehyde, 97%

MDL
MFCD02683546
EINECS
000-000-0

Chemical Properties

Formula
C6H4BrNO
Formula Weight
186.01
Melting point
79-83°
Sensitivity
Air Sensitive
Solubility
Soluble in dichloromethane, ether, ethyl acetate and methanol. Insoluble in water.

Applications

6-Bromopyridine-2-carboxaldehyde is used in the study of a rhodium-catalyzed, reductive aldol coupling with divinyl ketones leading to syn ß-hydroxyenones. It is also used as a building block for Tris[(pyridyl)methyl]amine ligands.

Notes

Store under inert gas. It is sensitive to air. Store in a cool, dry conditions in well sealed containers. Incompatible with oxidizing agents.

Literature References

Soo Bong Han.; Michael J Krische. Reductive aldol coupling of divinyl ketones via rhodium-catalyzed hydrogenation: syn-diastereoselective construction of beta-hydroxyenones. Organic Letters. 2006, 8 (24), 5657-5660.

Chao-Yu Wang, Yi-Hong Liu, Shei-Ming Peng, Shiuh-Tzung Liu. Rhodium(I) complexes containing a bulky pyridinyl N-heterocyclic carbene ligand: Preparation and reactivity. J. Org. ChemJournal of Organometallic Chemistry. 2006, 691 (19), 4012-4020.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P280g-P305+P351+P338

Wear protective gloves. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Other References

Beilstein
1524300
Harmonized Tariff Code
2933.39
TSCA
No

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