Cookies disclaimer

I agree Our site saves small pieces of text information (cookies) on your device in order to deliver better content and for statistical purposes. You can disable the usage of cookies by changing the settings of your browser. By browsing our website without changing the browser settings you grant us permission to store that information on your device.

L19681 (±)-1-Ferrocenylethanol, 99%

CAS Number
1277-49-2
Synonyms
1-Hydroxyethylferrocene
alpha-Methylferrocenemethanol

This item cannot be ordered online at this time. Please try again later, or request a bulk quote.

Bulk/Specialty

(±)-1-Ferrocenylethanol, 99%

MDL
MFCD00013752

Chemical Properties

Formula
C12H14FeO
Formula Weight
230.09
Melting point
77-79°
Flash Point
>100°(212°F)
Storage & Sensitivity
Ambient temperatures.
Solubility
Insoluble in water.

Applications

(+/-)-1-Ferrocenylethanol is a ligand in titanium-catalyzed intermolecular hydroamination of terminal alkynes (Markovnikov vs. anti-Markovnikov addition). Used as a reactant for single-electron transfer living radical polymerization reactions, preparation of ferrocene-modified thiopyrimidines as anticancer agents, preparation of rersible addition-fragmentation chain transfer (RAFT) agent for RAFT polymerization of styrene.

Notes

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from oxidizing agents.

Literature References

Neil W. Boaz. Enzymatic esterification of 1-ferrocenylethanol: An alternate approach to chiral ferrocenyl bis-phosphines. Tetrahedron Letters. 1989, 30, (16), 2061-2064.

Stanley I. Goldberg; William D. Loeble; Thomas T. Tidwell. Alumina-catalyzed dehydration of 1-ferrocenylethanol. Formation of 1,3-diferrocenyl-1-butene. J. Org. Chem. 1967, 32, (12), 4070-4071.

GHS Hazard and Precautionary Statements

Hazard Statements: H302-H315-H319-H335

Harmful if swallowed. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P264b-P270-P271-P280-P301+P312-P302+P352-P304+P340-P305+P351+P338-P312-P330-P332+P313-P362-P501c

Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Rinse mouth. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Harmonized Tariff Code
2931.90
TSCA
No
RTECS
LK0730000

Recommended

Recently Viewed

Chemicals

Life Science

Metals & Materials

Catalysts

Analytical & Labware