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1277-49-2 - (±)-1-Ferrocenylethanol, 99% - 1-Hydroxyethylferrocene - alpha-Methylferrocenemethanol - L19681 - Alfa Aesar

L19681 (±)-1-Ferrocenylethanol, 99%

CAS Number
1277-49-2
Synonyms
1-Hydroxyethylferrocene
alpha-Methylferrocenemethanol

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(±)-1-Ferrocenylethanol, 99%

MDL
MFCD00013752

Chemical Properties

Formula
C12H14FeO
Formula Weight
230.09
Melting point
77-79°
Flash Point
>100°(212°F)
Solubility
Insoluble in water.

Applications

(+/-)-1-Ferrocenylethanol is a ligand in titanium-catalyzed intermolecular hydroamination of terminal alkynes (Markovnikov vs. anti-Markovnikov addition). Used as a reactant for single-electron transfer living radical polymerization reactions, preparation of ferrocene-modified thiopyrimidines as anticancer agents, preparation of rersible addition-fragmentation chain transfer (RAFT) agent for RAFT polymerization of styrene.

Notes

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from oxidizing agents.

Literature References

Neil W. Boaz. Enzymatic esterification of 1-ferrocenylethanol: An alternate approach to chiral ferrocenyl bis-phosphines. Tetrahedron Letters. 1989, 30, (16), 2061-2064.

Stanley I. Goldberg; William D. Loeble; Thomas T. Tidwell. Alumina-catalyzed dehydration of 1-ferrocenylethanol. Formation of 1,3-diferrocenyl-1-butene. J. Org. Chem. 1967, 32, (12), 4070-4071.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P280a-P305+P351+P338-P304+P340-P312a-P321-P332+P313-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Specific treatment (see label). If skin irritation occurs: Get medical advice/attention. Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Harmonized Tariff Code
2931.90
TSCA
No
RTECS
LK0730000

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