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55700-44-2 - (R)-(-)-N,N-Dimethyl-1-[(S)-2-(diphenylphosphino)ferrocenyl]ethylamine, 97% - L19685 - Alfa Aesar

L19685 (R)-(-)-N,N-Dimethyl-1-[(S)-2-(diphenylphosphino)ferrocenyl]ethylamine, 97%

CAS Number
55700-44-2
Synonyms

Size Price ($) Quantity Availability
100mg 67.10
500mg 220.00
2g 741.00
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(R)-(-)-N,N-Dimethyl-1-[(S)-2-(diphenylphosphino)ferrocenyl]ethylamine, 97%

MDL
MFCD00075286

Chemical Properties

Formula
C26H28FeNP
Formula Weight
441.34
Melting point
141-143°
Sensitivity
Air Sensitive
Solubility
Insoluble in water.

Applications

(R)-(-)-N,N-Dimethyl-1-[(S)-2-(diphenylphosphino)ferrocenyl]ethylamine acts as a ligand used in the enantioselective vinylation of aldehydes.

Notes

Incompatible with strong oxidizing agents.

Literature References

Moschetta, E. G.; Gans, K. M.; Rioux, R. M. Elucidating the roles of enthalpy, entropy, and donor atom in the chelate effect for binding different bidentate ligands on the same metal center. J. Catal. 2014, 309, 11-20.

Li, W. N.; Wang, Z. L. Kumada-Tamao-Corriu cross-coupling reaction of O-based electrophiles with Grignard reagents via C-O bond activation. RSC Adv. 2013, 3 (48), 25565-25575.

GHS Hazard and Precautionary Statements

Hazard Statements: H302-H315-H319-H335

Harmful if swallowed. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P280-P305+P351+P338-P304+P340-P362-P301+P312-P312-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Harmonized Tariff Code
2931.90
TSCA
No

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