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(S)-(+)-N,N-Dimethyl-1-[(R)-2-(diphenylphosphino)ferrocenyl]ethylamine is the raw material of asymmetric hydrogenation chiral ligands.
Keiji Yamamoto; Junya Wakatsuki; Ryuichi Sugimoto. Modification of (S)-N,N-Dimethyl-1-[(R)-1?,2-bis(diphenylphosphino)ferrocenyl]ethylamine (BPPFA) as a Ligand for Asymmetric Hydrogenation of Olefins Catalyzed by a Chiral Rhodium(I) Complex. Bulletin of the Chemical Society of Japan. 1980, 53, (4), 1132-1137.
Masaharu Nakamura; Atsushi Hirai and Eiichi Nakamura. Iron-Catalyzed Olefin Carbometalation. J. Org. Chem. Soc. 2000, 125, (5), 978-979.
Hazard Statements: H301-H315-H319-H335
Toxic if swallowed. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.
Precautionary Statements: P261-P280a-P301+P310a-P305+P351+P338-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF SWALLOWED: Immediately call a POISON CENTER/doctor IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.