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55650-58-3 - (S)-(+)-N,N-Dimethyl-1-[(R)-2-(diphenylphosphino)ferrocenyl]ethylamine, 97% - L19686 - Alfa Aesar

L19686 (S)-(+)-N,N-Dimethyl-1-[(R)-2-(diphenylphosphino)ferrocenyl]ethylamine, 97%

CAS Number
55650-58-3
Synonyms

Size Price ($) Quantity Availability
100mg 25.68
500mg 88.34
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(S)-(+)-N,N-Dimethyl-1-[(R)-2-(diphenylphosphino)ferrocenyl]ethylamine, 97%

MDL
MFCD00075285

Chemical Properties

Formula
C26H28FeNP
Formula Weight
441.34
Melting point
141-143°
Sensitivity
Air Sensitive
Solubility
Insoluble in water.

Applications

(S)-(+)-N,N-Dimethyl-1-[(R)-2-(diphenylphosphino)ferrocenyl]ethylamine is the raw material of asymmetric hydrogenation chiral ligands.

Notes

Air sensitive. Store under inert gas. Store away from oxidizing agents, air.

Literature References

Keiji Yamamoto; Junya Wakatsuki; Ryuichi Sugimoto. Modification of (S)-N,N-Dimethyl-1-[(R)-1?,2-bis(diphenylphosphino)ferrocenyl]ethylamine (BPPFA) as a Ligand for Asymmetric Hydrogenation of Olefins Catalyzed by a Chiral Rhodium(I) Complex. Bulletin of the Chemical Society of Japan. 1980, 53, (4), 1132-1137.

Masaharu Nakamura; Atsushi Hirai and Eiichi Nakamura. Iron-Catalyzed Olefin Carbometalation. J. Org. Chem. Soc. 2000, 125, (5), 978-979.

GHS Hazard and Precautionary Statements

Hazard Statements: H301-H315-H319-H335

Toxic if swallowed. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P280-P301+P310-P305+P351+P338-P304+P340-P362-P312-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Harmonized Tariff Code
2931.90
TSCA
No

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