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3430-27-1 - 3-Amino-4-methylpyridine, 98% - 3-Amino-4-picoline - 4-Methyl-3-pyridinamine - L19730 - Alfa Aesar

L19730 3-Amino-4-methylpyridine, 98%

CAS Number
3430-27-1
Synonyms
3-Amino-4-picoline
4-Methyl-3-pyridinamine

Size Price ($) Quantity Availability
5g 58.40
25g 204.00
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3-Amino-4-methylpyridine, 98%

MDL
MFCD00128871

Chemical Properties

Formula
C6H8N2
Formula Weight
108.14
Melting point
102-106°
Boiling Point
254°
Sensitivity
Hygroscopic

Literature References

Ortho-lithiation with t-BuLi of the Boc-protected amine followed by addition of a Weinreb amide gave the 2-alkyl substituted 5-azaindole in good yield: J. Heterocycl. Chem., 29, 359 (1992), whereas DMF gave 6-azaindole in high yield: Synthesis, 877 (1996). 2-Substituted 6-azaindoles have also been synthesized in one step by direct dilithiation with s-BuLi, followed by reaction with an ester: J. Org, Chem., 70, 6512 (2005).

/n

GHS Hazard and Precautionary Statements

Hazard Statements: H301-H311-H315-H319-H335

Toxic if swallowed. Toxic in contact with skin. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P280h-P305+P351+P338-P307+P311

Wear protective gloves/clothing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF exposed: Call a POISON CENTER or doctor/physician.

Other References

Beilstein
107792
Hazard Class
6.1
Packing Group
III
Harmonized Tariff Code
2933.39
TSCA
No

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