Cookies disclaimer

I agree Our site saves small pieces of text information (cookies) on your device in order to deliver better content and for statistical purposes. You can disable the usage of cookies by changing the settings of your browser. By browsing our website without changing the browser settings you grant us permission to store that information on your device.

L19759 1,1'-Bis(di-tert-butylphosphino)ferrocene, 98%

CAS Number
84680-95-5
Synonyms

Stock No. Size Price ($) Quantity Availability
L19759-ME 500mg 65.20
L19759-04 2g 230.00
Add to Cart Bulk/Specialty Print Quote View Item

1,1'-Bis(di-tert-butylphosphino)ferrocene, 98%

MDL
MFCD01630818

Chemical Properties

Formula
C26H44FeP2
Formula Weight
474.43
Melting point
73-78°
Storage & Sensitivity
Air Sensitive. Store under Argon. Ambient temperatures.
Solubility
Insoluble in water.

Applications

The rate of palladium-catalyzed amination of unactivated aryl chlorides is accelerated by sterically hindered chelating alkyl phosphines, ie, 1,1'-bis(di-tert-butylphosphino)ferrocene.

Notes

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents.

Literature References

Hanh Nho Nguyen,; Xiaohua Huang,; Stephen L. Buchwald. The First General Palladium Catalyst for the Suzuki-Miyaura and Carbonyl Enolate Coupling of Aryl Arenesulfonates. J. Am. Chem. Soc.. 2003, 125 (39), 11818-11819.

Fawn N. Blanco,; Laura E. Hagopian,; William R. McNamara,; James A. Golen,; Arnold L. Rheingold,; Chip Nataro. Anodic Electrochemistry of Free and Coordinated 1,1‘-Bis(di-tert-butylphosphino)ferrocene. Organometallics. 2006, 25 (18), 4292-4300.

GHS Hazard and Precautionary Statements

Hazard Statements: H302-H315-H319-H335

Harmful if swallowed. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P264b-P270-P271-P280-P301+P312-P302+P352-P304+P340-P305+P351+P338-P312-P330-P332+P313-P362-P501c

Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Rinse mouth. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Harmonized Tariff Code
2931.39
TSCA
No

Recommended

  • H27015

    2-Dicyclohexylphosphino-2',6'-dimethoxybiphenyl, 98+%
  • L02589

    N-Methyliminodiacetic acid, 99%
  • L09549

    1-Phenyl-2-propyn-1-ol, 98%
  • L19752

    Tri-tert-butylphosphonium tetrafluoroborate, 97%
  • 41225

    Dichloro[1,1'-bis(diphenylphosphino)ferrocene]palladium(II), complex with dichloromethane (1:1), Pd 13%

Recently Viewed

Chemicals

Life Science

Metals & Materials

Catalysts

Analytical & Labware