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An ionic liquid, 1-ethyl-3-methylimidazolium bromide is used as reaction medium for the synthesis and crystallization of a coordination polymer, (EMI)[Cd(BTC)]. 1-ethyl-3-methylimidazolium bromide was used as a solvent in [emim] 2 [Cd 2 (btec)Br 2 ]. Form the diene complexation; carbonyl insertion; cycloaddition; reduction and deoxygenation.
Mohammed Taghi Zafarani-Moattar,; Shokat Sarmad. Effect of tri-potassium phosphate on volumetric, acoustic, and transport behaviour of aqueous solutions of 1-ethyl-3-methylimidazolium bromide at T = (298.15 to 318.15) K. The Journal of Chemical Thermodynamics. 2010, 42 (10), 1213-1221.
Steven D. Chambreau,; Jerry A. Boatz,; Ghanshyam L. Vaghjiani,; Christine Koh,; Oleg Kostko?.Thermal Decomposition Mechanism of 1-Ethyl-3-methylimidazolium Bromide Ionic Liquid. J. Phys. Chem. A. 2012 , 116 (24), 5867-5876.
Hazard Statements: H315-H319
Causes skin irritation. Causes serious eye irritation.
Precautionary Statements: P280a-P264-P305+P351+P338-P321-P332+P313-P337+P313
Wear protective gloves and eye/face protection. Wash thoroughly after handling. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Specific treatment (see label). If skin irritation occurs: Get medical advice/attention. If eye irritation persists: