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An ionic liquid, 1-ethyl-3-methylimidazolium bromide is used as reaction medium for the synthesis and crystallization of a coordination polymer, (EMI)[Cd(BTC)]. 1-ethyl-3-methylimidazolium bromide was used as a solvent in [emim] 2 [Cd 2 (btec)Br 2 ]. Form the diene complexation; carbonyl insertion; cycloaddition; reduction and deoxygenation.
Mohammed Taghi Zafarani-Moattar,; Shokat Sarmad. Effect of tri-potassium phosphate on volumetric, acoustic, and transport behaviour of aqueous solutions of 1-ethyl-3-methylimidazolium bromide at T = (298.15 to 318.15) K. The Journal of Chemical Thermodynamics. 2010, 42 (10), 1213-1221.
Steven D. Chambreau,; Jerry A. Boatz,; Ghanshyam L. Vaghjiani,; Christine Koh,; Oleg Kostko?.Thermal Decomposition Mechanism of 1-Ethyl-3-methylimidazolium Bromide Ionic Liquid. J. Phys. Chem. A. 2012 , 116 (24), 5867-5876.
Hazard Statements: H315-H319-H335-H500
Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation. May form combustible dust concentrations in air
Precautionary Statements: P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P337+P313-P362-P501c
Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant