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39856-58-1 - 3-Amino-2-bromopyridine, 98% - 2-Bromo-3-pyridinamine - L19839 - Alfa Aesar

L19839 3-Amino-2-bromopyridine, 98%

CAS Number
39856-58-1
Synonyms
2-Bromo-3-pyridinamine

Size Price ($) Quantity Availability
1g 32.72
5g 123.08
25g 408.80
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3-Amino-2-bromopyridine, 98%

MDL
MFCD00234064
EINECS
000-000-0

Chemical Properties

Formula
C5H5BrN2
Formula Weight
173.01
Melting point
75-79°
Solubility
Slightly soluble in water.

Applications

Used in a palladium-catalyzed synthesis of indole systems containing fused medium- and large-ring heterocycles. pyrrole derivatives ahs been prepared using 3-Amino-2-bromopyridine. Used in P-C coupling reaction.

Notes

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents.

Literature References

Mohamed Shaker S. Adam,; Olaf Kühl,; Markus K. Kindermann,; Joachim W. Heinicke,; Peter G. Jones. 3-Amino- and 3-acylamido-2-phosphonopyridines: synthesis by Pd-catalyzed P-C coupling, structure and conversion to pyrido[b]-anellated Pdouble bond; length as m-dashC-N heterocycles. Tetrahedron. 2008, 64(34), 7960-7967.

GHS Hazard and Precautionary Statements

Hazard Statements: H302-H312-H332-H315-H319-H335

Harmful if swallowed. Harmful in contact with skin. Harmful if inhaled. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P280-P305+P351+P338-P304+P340-P362-P301+P312-P312-P363-P405-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. Wash contaminated clothing before reuse. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
109830
Harmonized Tariff Code
2933.39
TSCA
No

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