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51857-17-1 - N-Boc-1,6-diaminohexane, 98% - N-(tert-Butoxycarbonyl)hexamethylenediamine - tert-Butyl N-(6-aminohexyl)carbamate - L19948 - Alfa Aesar

L19948 N-Boc-1,6-diaminohexane, 98%

CAS Number
51857-17-1
Synonyms
N-(tert-Butoxycarbonyl)hexamethylenediamine
tert-Butyl N-(6-aminohexyl)carbamate

Size Price ($) Quantity Availability
1g 43.20
5g 133.00
25g 521.00
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N-Boc-1,6-diaminohexane, 98%

MDL
MFCD00671489
EINECS
000-000-0

Chemical Properties

Formula
(CH3)3COCONH(CH2)6NH2
Formula Weight
216.33
Boiling Point
106-110°/0.3mm
Flash Point
>110°(230°F)
Density
0.965
Refractive Index
1.4620
Sensitivity
Air Sensitive
Solubility
Soluble in dichloromethane and ethyl acetate.

Applications

N-Boc-1,6-diaminohexane is used to prepare 1,3-Bis[6-(Boc-amino)hexyl]urea by reacting with carbonyl dichloride in the presence of triethylamine. Further, it is used as a reagent for the introduction of a C6-spacer.

Notes

Air sensitive. Incompatible with strong oxidizing agents.

Literature References

Jong, T.; Bradley, M. Flow-Mediated Synthesis of Boc, Fmoc, and Ddiv Monoprotected Diamines. Org. Lett. 2015, 17 (3), 422-425.

Jong, T.; Pérez-López, A. M.; Johansson, E. M. V.; Lilienkampf, A.; Bradley, M. Flow and Microwave-Assisted Synthesis of N-(Triethylene glycol)glycine Oligomers and Their Remarkable Cellular Transporter Activities. Bioconjugate Chem. 2015, 26 (8), 1759-1765.

GHS Hazard and Precautionary Statements

Hazard Statements: H314-H318

Causes severe skin burns and eye damage. Causes serious eye damage.

Precautionary Statements: P260u-P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P310a-P363-P405-P501a

Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Wash contaminated clothing before reuse. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
2089264
Hazard Class
8
Packing Group
III
Harmonized Tariff Code
2924.19
TSCA
No

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