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L19962 Isopropylboronic acid, 98%

CAS Number
80041-89-0
Synonyms
2-Propaneboronic acid

Stock No. Size Price ($) Quantity Availability
L19962-03 1g 28.30
L19962-06 5g 87.30
L19962-14 25g 307.00
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Isopropylboronic acid, 98%

MDL
MFCD01319021

Chemical Properties

Formula
C3H9BO2
Formula Weight
87.91
Storage & Sensitivity
Keep Cold. Hygroscopic.
Solubility
Soluble in water.

Applications

Isopropylboronic acid as a reagent is involved in copper-promoted cross-coupling, Domino Heck-Suzuki reactions, Suzuki-Miyaura type couple reactions and alkylation-hydride reduction sequence.

Notes

Hygroscopic. Incompatible with oxidizing agents.

Literature References

Thorsten Wilhelm; Mark Lautens. Palladium-catalyzed alkylation-hydride reduction sequence: synthesis of meta-substituted arenes. Organic Letters. 2005, 7,(18), 4053-4056.

 

Adri van den Hoogenband; Jos H.M.Lange; Jan Willem Terpstra; Melle Koch; Gerben M.Visser; Martin Visser; Ties J.Korstanje; Johann T.B.H.Jastrzebski. Ruphos-mediated Suzuki cross-coupling of secondary alkyl trifluoroborates. Tetrahedron Letters. 2008, 49,(26), 4122-4124.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P362-P501c

Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
1731883
Harmonized Tariff Code
2931.90
TSCA
No

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