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5315-25-3 - 2-Bromo-6-methylpyridine, 98% - 6-Bromo-2-picoline - L20018 - Alfa Aesar

L20018 2-Bromo-6-methylpyridine, 98%

CAS Number
5315-25-3
Synonyms
6-Bromo-2-picoline

Size Price ($) Quantity Availability
5g 61.30
25g 254.00
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2-Bromo-6-methylpyridine, 98%

MDL
MFCD00040743
EINECS
226-173-4

Chemical Properties

Formula
C6H6BrN
Formula Weight
172.03
Boiling Point
102-103°/20mm
Flash Point
97°(206°F)
Density
1.512
Refractive Index
1.5625
Solubility
Soluble in chloroform, ethyl aceate. Not miscible or difficult to mix with water.

Applications

6-Bromo-2-picoline is a halogenated pyridine derivative used is a building block in the preparation of nitrogen containing heterocyclic compounds. It may used in following synthesis 6,6?-dimethyl-2,2?-bipyridine, 6-methyl-2-pyridyl-2-pyridylmethanone, 2-methyl-6-(trimethylsilyl)-pyridine and N,N’-bis-(6-methylpyrid-2-yl)-(1R,2R)-1,2- diaminocyclohexane (cydiampy).

Notes

Store in cool, dry place in tightly closed container. With adequate ventilation. Store away from oxidizing agent.

Literature References

Rajalakshmanan E and Alexander V. Synthesis of Dimethylbipyridines by the Reductive Coupling of 2-Halomethylpyridines with Nickel Catalyst. Synth. Commun. 2005,35(6), 891-895.

Abarca B, et al. 3-(2-Pyridyl)-[1,2,3] triazolo [1,5-a] pyridines. An experimental and theoretical (DFT) study of the ring-chain isomerization. Org. Biomol. Chem. 2005,3(21), 3905-3910.

GHS Hazard and Precautionary Statements

Hazard Statements: H301-H311-H332-H315-H319

Toxic if swallowed. Toxic in contact with skin. Harmful if inhaled. Causes skin irritation. Causes serious eye irritation.

Precautionary Statements: P261-P280-P301+P310a-P305+P351+P338-P405-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Immediately call a POISON CENTER/doctor IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
107322
Harmonized Tariff Code
2933.39
TSCA
No

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