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L20018 2-Bromo-6-methylpyridine, 98%

CAS Number
5315-25-3
Synonyms
6-Bromo-2-picoline

Stock No. Size Price ($) Quantity Availability
L20018-06 5g 58.20
L20018-14 25g 237.00
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2-Bromo-6-methylpyridine, 98%

MDL
MFCD00040743
EINECS
226-173-4

Chemical Properties

Formula
C6H6BrN
Formula Weight
172.03
Boiling Point
102-103°/20mm
Flash Point
97°(206°F)
Density
1.512
Refractive Index
1.5625
Storage & Sensitivity
Ambient temperatures.
Solubility
Soluble in chloroform, ethyl aceate. Not miscible or difficult to mix with water.

Applications

6-Bromo-2-picoline is a halogenated pyridine derivative used is a building block in the preparation of nitrogen containing heterocyclic compounds. It may used in following synthesis 6,6?-dimethyl-2,2?-bipyridine, 6-methyl-2-pyridyl-2-pyridylmethanone, 2-methyl-6-(trimethylsilyl)-pyridine and N,N’-bis-(6-methylpyrid-2-yl)-(1R,2R)-1,2- diaminocyclohexane (cydiampy).

Notes

Store in cool, dry place in tightly closed container. With adequate ventilation. Store away from oxidizing agent.

Literature References

Rajalakshmanan E and Alexander V. Synthesis of Dimethylbipyridines by the Reductive Coupling of 2-Halomethylpyridines with Nickel Catalyst. Synth. Commun. 2005,35(6), 891-895.

Abarca B, et al. 3-(2-Pyridyl)-[1,2,3] triazolo [1,5-a] pyridines. An experimental and theoretical (DFT) study of the ring-chain isomerization. Org. Biomol. Chem. 2005,3(21), 3905-3910.

GHS Hazard and Precautionary Statements

Hazard Statements: H302+H312+H332-H315-H319-H335

Harmful if swallowed. Harmful in contact with skin. Harmful if inhaled. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P264b-P270-P271-P280-P301+P312-P302+P352-P304+P340-P305+P351+P338-P312-P330-P332+P313-P362-P501c

Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Rinse mouth. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
107322
Harmonized Tariff Code
2933.39
TSCA
No

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