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Cerium(IV) trifluoromethanesulfonate, is used as a strong oxidizing agent, in the oxidation of benzyl alcohols and alkylbenzenes to aryl aldehydes and aryl ketones respectively. It can also be used as a catalyst for high-yield deprotection of tert-butyldimethylsilyl ethers
Tsuneo Imamoto; Yasuhiro Koide; Susumu Hiyama. Cerium(IV) Trifluoromethanesulfonate as a Strong Oxidizing Agent. Chemistry Letters. 1990, 19(8),1445-1446
Giuseppe Bartoli; Giovanna Cupone; Renato Dalpozzo; Antonio De Nino; Loredana Maiuolo; Antonio Procopio; Letizia Sambri; Antonio Tagarelli. Deprotection of t-butyldimethylsilyl ethers promoted by cerium(IV) triflate. Tetrahedron Letters. 2002, 43(34), 5945-5947.
Catalyst for high-yield deprotection of tert-butyldimethylsilyl ethers: Tetrahedron Lett., 43, 5945 (2002).
The uses of rare-earth metal triflates in organic synthesis have been reviewed by S. Kobayashi: Synlett, 689 (1994); Chem. Rev., 102, 2227 (2002).
Hazard Statements: H315-H319-H335
Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.
Precautionary Statements: P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.